标准编号:	GB 37822-2019
中文名称:	挥发性有机物无组织排放控制标准
英文名称:	Standard for fugitive emission of volatile organic compounds
中标分类:	Z60    污染物排放综合
行业分类:	GB    国家标准
ICS分类:	13.040.40 13.040.40    固定源排放限值 13.040.40
发布机构:	中华人民共和国生态环境部 国家市场监督管理总局
发布日期:	2019-05-24
实施日期:	2019-7-1
标准状态:	valid
翻译语言:	英文
文件格式:	PDF
中文字符数:	20000 字
翻译价格(元):	1090.0
交付时间:	付款后 1 个工作日

Codeofchina.com is in charge of this English translation. In case of any doubt about the English translation, the Chinese original shall be considered authoritative. This standard is developed with a view to implementing the Environmental protection law of the People's Republic of China and the Law of the People's Republic of China on the prevention and control of atmospheric pollution, controlling environment pollution, improving environmental quality and enhancing control and management of fugitive emission of VOCs. This standard specifies the fugitive emission control requirements for VOCs-containing materials storage, VOCs-containing materials transfer and transport and VOCs-containing materials in technological process, as well as VOCs leakage control requirements for equipment and pipeline components, the fugitive emission control requirements for VOCs on uncovered liquid surface, as well as requirements for collection and treatment system of exhaust gas via fugitive emission of VOCs and pollution monitoring requirements for the company's plant and surrounding areas. This standard is issued for the first time. The fugitive emission control of VOCs shall be executed in accordance with the provisions of this standard by new facilities since July 1, 2019, and by the existing facilities since July 1, 2020. Upon approval of provincial people's government, all regions may implement this standard in advance according to the need of local environmental protection and economic and technical conditions. This standard specifies the basic requirements for fugitive emission of VOCs. Local provincial people's government may formulate local pollutant emission standards for the items not specified in this standard; and it may also formulate local pollutant emission standards stricter than this standard for the items specified in this standard. Annex A of this standard is informative. This standard is developed by the Department of Air Environment and the Department of Laws and Regulations and Standards under the Ministry of Ecology and Environment. This standard was approved by the Ministry of Ecology and Environment on April 16, 2019. This standard is implemented from July 1, 2019. The Ministry of Ecology and Environment is in charge of the explanation of this standard. Standard for fugitive emission of volatile organic compounds 1 Application scope This standard specifies the fugitive emission control requirements for VOCs-containing materials storage, VOCs-containing materials transfer and transport and VOCs-containing materials in technological process, as well as VOCs leakage control requirements for equipment and pipeline components, the fugitive emission control requirements for VOCs on uncovered liquid surface, as well as requirements for collection and treatment system of exhaust gas via fugitive emission of VOCs and pollution monitoring requirements for the company's plant and surrounding areas. This standard is applicable to the fugitive emission management of VOCs in existing facilities or production facilities involving fugitive emission of VOCs, as well as the environmental impact assessment, the environmental protection facilities design, the completion environment protection acceptance, and the emission permit issuance of construction projects involving fugitive emissions of VOCs, and fugitive emission management of VOCs after their production. If the national pollutant emission standards issued by the state have stipulated the fugitive emission control of VOCs, they shall be implemented according to the industry pollutant emission standards. If the VOCs fugitive emission control requirements specified in this standard cannot be met due to safety factors or special process requirements, other equivalent pollution control measures may be taken and reported to the local ecological environment authority or implemented in accordance with the relevant requirements of the pollutant emission permit. 2 Normative references The following normative documents contain provisions which, through reference in this text, constitute provisions of this standard. For undated references, the latest edition of the normative document applies. GB 16297 Comprehensive emission standard of air pollutants GB/T 8017 Standard test method for vapor pressure of petroleum products (Reid method) GB/T 16157 The determination of particulates and sampling methods of gaseous pollutants emitted from exhaust gas of stationary source GB/T 16758 The classification and technical specification of exhaust hood HJ 38 Stationary source emission - Determination of total hydrocarbons, methane and nonmethane hydrocarbons - Gas chromatography HJ/T 55 Technical guidelines for fugitive emission monitoring of air pollutants HJ/T 397 Technical specifications for emission monitoring of stationary source HJ 501 Water quality - Determination of total organic carbon - Combustion oxidation nondispersive infrared absorption method HJ 604 Ambient air - Determination of total hydrocarbons, methane and nonmethane hydrocarbons - Direct injection/Gas chromatography HJ 732 Emission from stationary sources - Sampling of volatile organic compounds - Bags method HJ 733 Guideline for the determination of volatile organic compound leaks and uncovered liquid surface emissions HJ 819 Self-monitoring technology guidelines for pollution sources - General rule HJ 1012 Ambient air and stationary source emission - Specifications and test procedures for hydrocarbons, methane and nonmethane hydrocarbons portable total monitoring instrument HJ 1013 Specifications and test procedures for nonmethane hydrocarbons continuous emission monitoring system in stationary sources AQ/T 4274-2016 Technical specifications for test and evaluation of capture velocity for local exhaust ventilation facilities Measures for Automatic Monitoring and Management of Pollution Sources (Decree No.28 of the State Environmental Protection Administration) Measures for the Administration of Environmental Monitoring (Decree No.39 of the State Environmental Protection Administration) 3 Terms and definitions For the purposes of this standard, the following terms and definitions apply. 3.1 volatile organic compounds (VOCs) an organic compound that participates in atmospheric photochemical reactions, or determined in accordance with relevant provisions In characterizing the overall emissions of VOCs, total volatile organic compounds (expressed as TVOC) and non-methane total hydrocarbons (expressed as NMHC) can be used as pollutant control items based on industry characteristics and environmental management requirements. 3.2 total volatile organic compounds (TVOC) its total amount is the sum of the individual VOCs in the exhaust gas is measured with the specific monitoring method, which is calculated with the mass concentrations of the individual VOCs, in actual work, it is the sum of the individual VOCs, which account for more than 90% of the total, measured according to the expected analysis results 3.3 non-methane hydrocarbons (NMHC) its total amount is the sum of gaseous organic compounds other than methane, responsive to the hydrogen flame ionization detector, based on the mass concentration of carbon 3.4 fugitive emission irregular emission that atmospheric pollutants do not pass through the stack, including the effusion of open workplaces, as well as emissions through gaps, vents, open doors and windows and similar openings (holes) 3.5 closed/close the state or working mode that contaminants are not in contact with ambient air, or are separated from ambient air by sealing materials or sealing equipment 3.6 closed space a closed area or enclosed building formed by a confined structure that blocks pollutants, workplaces, etc. from the surrounding space The windows another opening (hole) of enclosed areas or enclosed buildings shall be kept closed at all times except for the time for entry and leaving of personnel, vehicles, equipment, materials, and stack and vents established according to the law. 3.7 VOCs-containing materials materials with a VOCs mass ratio of 10% or more, and organic polymer materials in this standard The terms of VOCs containing raw and auxiliary materials, VOCs-containing products and VOCs-containing wastes (slag, liquid) in this standard have the same meaning as VOCs-containing materials. 3.8 volatile organic liquid any organic liquid that emits VOCs into the atmosphere and meets one of the following conditions: (1) a single component organic liquid with a true vapor pressure of 0.3 kPa or more; (2) an organic liquid with a true vapor pressure of 0.3 kPa or more and a total mass of 20% or more in the mixture. 3.9 true vapor pressure the saturated vapor pressure (absolute pressure) at the working (storage) temperature of the organic liquid, or the vapor pressure with the liquid vaporization rate of the organic mixture as zero, also known as the bubble point vapor pressure, which can be converted according to the corresponding measurement method specified in GB/T 8017 Note: The working (storage) temperature of an organic liquid that is operated (stored) at normal temperature is calculated as the maximum monthly mean temperature of the year. 3.10 liquid-mounted seal the seal form with the edge of the floating roof is sealed immersed in the liquid surface of the storage material, also known as a liquid mosaic seal 3.11 mechanical shoe seal the seal form with the metal sheet vertically pressed against the storage tank wall by a spring or counterweight lever 3.12 double seals the seal form with a two-layer seal arranged between the edge of the floating roof and the inner wall of the storage tank, which is also called a double-sealed seal The lower seal is called a primary seal and the upper seal is called a secondary seal. 3.13 vapor balancing system a gas connection and balancing system arranged between the loading facility and the storage tank or between the storage tanks. 3.14 leakage detection value the net value of the VOCs concentration of the equipment and pipeline components detected by the instrument with the specified monitoring method deducted by the environmental background value, expressed as the mole fraction of carbon 3.15 open recirculating cooling water system a circulating cooling water system with circulates cooling water in direct contact with the atmosphere 3.16 existing facility industrial enterprises or production facilities that have been established and put into production and whose environmental impact assessment documents have been approved or filed before the date of implementation of this standard 3.17 new facility new, rebuilt and extended construction projects whose environmental impact assessment documents are approved from the implementation date of this standard 3.18 key regions the regions with severe air pollution, or fragile ecological environment, or need for further improvement of ambient air quality and in need for strict control of air pollutant emissions, according to the requirements of environmental protection work 3.19 stack height the height from the ground level of the stack (or its main building structure) to the outlet of the stack, m 3.20 enterprise boundary the legal boundary of the enterprise or production facility If it is difficult to determine the legal boundary, it refers to the actual land occupation boundary of the enterprise or production facility. 4 Scope and time of execution 4.1 The fugitive emission control of VOCs shall be executed in accordance with the provisions of this standard by new facilities since July 1, 2019, and by the existing facilities since July 1, 2020. 4.2 Enterprises in key regions shall implement the special control requirements for fugitive emission, and the geographical scope and time of execution shall be stipulated by the competent department of ecological environment under the State Council or the provincial people's government.

Foreword i 1 Application scope 2 Normative references 3 Terms and definitions 4 Scope and time of execution 5 Fugitive emission control requirements for VOCs-containing materials storage 6 Fugitive emission control requirements for VOCs-containing materials transfer and transport 7 Fugitive emission control requirements for VOCs-containing materials in technological process 8 VOCs leakage control requirements for equipment and pipeline components 9 Fugitive emission control requirements for fugitive emission of VOCs on uncovered liquid surface 10 Requirements for collection and treatment system of exhaust gas via fugitive emission of VOCs 11 Pollution monitoring requirements for the company's plant and its surrounding area 12 Pollutant monitoring requirements 13 Implementation and supervision Annex A (Informative) Monitoring requirements for fugitive emission of VOCs in the plant

挥发性有机物无组织排放控制标准 1 适用范围 本标准规定了VOCs物料储存无组织排放控制要求、VOCs物料转移和输送无组织排放控制要求、工艺过程VOCs无组织排放控制要求、设备与管线组件VOCs泄漏控制要求、敞开液面VOCs无组织排放控制要求，以及VOCs无组织排放废气收集处理系统要求、企业厂区内及周边污染监控要求。 本标准适用于涉及VOCs无组织排放的现有企业或生产设施的VOCs无组织排放管理，以及涉及VOCs无组织排放的建设项目的环境影响评价、环境保护设施设计、竣工环境保护验收、排污许可证核发及其投产后的VOCs无组织排放管理。 国家发布的行业污染物排放标准中对VOCs无组织排放控制已作规定的，按行业污染物排放标准执行。 因安全因素或特殊工艺要求不能满足本标准规定的VOCs无组织排放控制要求，可采取其他等效污染控制措施，并向当地生态环境主管部门报告或依据排污许可证相关要求执行。 2 规范性引用文件 本标准引用了下列文件或其中的条款。凡是未注明日期的引用文件，其最新版本适用于本标准。 GB 16297 大气污染物综合排放标准 GB/T 8017 石油产品蒸气压的测定 雷德法 GB/T 16157 固定污染源排气中颗粒物测定与气态污染物采样方法 GB/T 16758 排风罩的分类及技术条件 HJ 38 固定污染源废气 总烃、甲烷和非甲烷总烃的测定 气相色谱法 HJ/T 55 大气污染物无组织排放监测技术导则 HJ/T 397 固定源废气监测技术规范 HJ 501 水质 总有机碳的测定 燃烧氧化-非分散红外吸收法 HJ 604 环境空气 总烃、甲烷和非甲烷总烃的测定 直接进样-气相色谱法 HJ 732 固定污染源废气 挥发性有机物的采样 气袋法 HJ 733 泄漏和敞开液面排放的挥发性有机物检测技术导则 HJ 819 排污单位自行监测技术指南 总则 HJ 1012 环境空气和废气 总烃、甲烷和非甲烷总烃便携式监测仪技术要求及检测方法 HJ 1013 固定污染源废气非甲烷总烃连续监测系统技术要求及检测方法 AQ/T 4274—2016 局部排风设施控制风速检测与评估技术规范 《污染源自动监控管理办法》（国家环境保护总局令 第28号） 《环境监测管理办法》（国家环境保护总局令 第39号） 3 术语和定义 下列术语和定义适用于本标准。 3.1 挥发性有机物 volatile organic compounds（VOCs） 参与大气光化学反应的有机化合物，或者根据有关规定确定的有机化合物。 在表征VOCs总体排放情况时，根据行业特征和环境管理要求，可采用总挥发性有机物（以TVOC表示）、非甲烷总烃（以NMHC表示）作为污染物控制项目。 3.2 总挥发性有机物 total volatile organic compounds（TVOC） 采用规定的监测方法，对废气中的单项VOCs物质进行测量，加和得到VOCs物质的总量，以单项VOCs物质的质量浓度之和计。实际工作中，应按预期分析结果，对占总量90%以上的单项VOCs物质进行测量，加和得出。 3.3 非甲烷总烃 non-methane hydrocarbons（NMHC） 采用规定的监测方法，氢火焰离子化检测器有响应的除甲烷外的气态有机化合物的总和，以碳的质量浓度计。 3.4 无组织排放 fugitive emission 大气污染物不经过排气筒的无规则排放，包括开放式作业场所逸散，以及通过缝隙、通风口、敞开门窗和类似开口（孔）的排放等。 3.5 密闭 closed/close 污染物质不与环境空气接触，或通过密封材料、密封设备与环境空气隔离的状态或作业方式。 3.6 密闭空间 closed space 利用完整的围护结构将污染物质、作业场所等与周围空间阻隔所形成的封闭区域或封闭式建筑物。该封闭区域或封闭式建筑物除人员、车辆、设备、物料进出时，以及依法设立的排气筒、通风口外，门窗及其他开口（孔）部位应随时保持关闭状态。 3.7 VOCs物料 VOCs-containing materials 本标准是指VOCs质量占比大于等于10%的物料，以及有机聚合物材料。 本标准中的含VOCs原辅材料、含VOCs产品、含VOCs废料（渣、液）等术语的含义与VOCs物料相同。 3.8 挥发性有机液体 volatile organic liquid 任何能向大气释放VOCs的符合下列条件之一的有机液体： （1）真实蒸气压大于等于0.3 kPa的单一组分有机液体； （2）混合物中，真实蒸气压大于等于0.3 kPa的组分总质量占比大于等于20%的有机液体。 3.9 真实蒸气压 true vapor pressure 有机液体工作（储存）温度下的饱和蒸气压（绝对压力），或者有机混合物液体气化率为零时的蒸气压，又称泡点蒸气压，可根据GB/T 8017等相应测定方法换算得到。 注：在常温下工作（储存）的有机液体，其工作（储存）温度按常年的月平均气温最大值计算。 3.10 浸液式密封 liquid-mounted seal 浮顶的边缘密封浸入储存物料液面的密封形式，又称液体镶嵌式密封。 3.11 机械式鞋形密封 mechanical shoe seal 通过弹簧或配重杠杆使金属薄板垂直紧抵于储罐罐壁上的密封形式。 3.12 双重密封 double seals 浮顶边缘与储罐内壁间设置两层密封的密封形式，又称双封式密封。下层密封称为一次密封，上层密封称为二次密封。 3.13 气相平衡系统 vapor balancing system 在装载设施与储罐之间或储罐与储罐之间设置的气体连通与平衡系统。 3.14 泄漏检测值 leakage detection value 采用规定的监测方法，检测仪器探测到的设备与管线组件泄漏点的VOCs浓度扣除环境本底值后的净值，以碳的摩尔分数表示。 3.15 开式循环冷却水系统 open recirculating cooling water system 循环冷却水与大气直接接触散热的循环冷却水系统。 3.16 现有企业 existing facility 本标准实施之日前已建成投产或环境影响评价文件已通过审批或备案的工业企业或生产设施。 3.17 新建企业 new facility 自本标准实施之日起环境影响评价文件通过审批或备案的新建、改建和扩建的工业建设项目。 3.18 重点地区 key regions 根据环境保护工作要求，对大气污染严重，或生态环境脆弱，或有进一步环境空气质量改善需求等，需要严格控制大气污染物排放的地区。 3.19 排气筒高度 stack height 自排气筒（或其主体建筑构造）所在的地平面至排气筒出口计的高度，单位为m。 3.20 企业边界 enterprise boundary 企业或生产设施的法定边界。若难以确定法定边界，则指企业或生产设施的实际占地边界。 4 执行范围与时间 4.1 新建企业自2019年7月1日起，现有企业自2020年7月1日起，VOCs无组织排放控制按照本标准的规定执行。 4.2 重点地区的企业执行无组织排放特别控制要求，执行的地域范围和时间由国务院生态环境主管部门或省级人民政府规定。 5 VOCs物料储存无组织排放控制要求 5.1 基本要求 5.1.1 VOCs物料应储存于密闭的容器、包装袋、储罐、储库、料仓中。 5.1.2 盛装VOCs物料的容器或包装袋应存放于室内，或存放于设置有雨棚、遮阳和防渗设施的专用场地。盛装VOCs物料的容器或包装袋在非取用状态时应加盖、封口，保持密闭。 5.1.3 VOCs物料储罐应密封良好，其中挥发性有机液体储罐应符合5.2条规定。 5.1.4 VOCs物料储库、料仓应满足3.6条对密闭空间的要求。 5.2 挥发性有机液体储罐 5.2.1 储罐控制要求 5.2.1.1 储存真实蒸气压≥76.6 kPa且储罐容积≥75 m3的挥发性有机液体储罐，应采用低压罐、压力罐或其他等效措施。 5.2.1.2 储存真实蒸气压≥27.6 kPa但＜76.6 kPa且储罐容积≥75 m3的挥发性有机液体储罐，应符合下列规定之一： a）采用浮顶罐。对于内浮顶罐，浮顶与罐壁之间应采用浸液式密封、机械式鞋形密封等高效密封方式；对于外浮顶罐，浮顶与罐壁之间应采用双重密封，且一次密封应采用浸液式密封、机械式鞋形密封等高效密封方式。 b）采用固定顶罐，排放的废气应收集处理并满足相关行业排放标准的要求（无行业排放标准的应满足GB 16297的要求），或者处理效率不低于80%。 c）采用气相平衡系统。 d）采取其他等效措施。 5.2.2 储罐特别控制要求 5.2.2.1 储存真实蒸气压≥76.6 kPa的挥发性有机液体储罐，应采用低压罐、压力罐或其他等效措施。 5.2.2.2 储存真实蒸气压≥27.6 kPa但＜76.6 kPa且储罐容积≥75 m3的挥发性有机液体储罐，以及储存真实蒸气压≥5.2 kPa但＜27.6 kPa且储罐容积≥150 m3的挥发性有机液体储罐，应符合下列规定之一： a）采用浮顶罐。对于内浮顶罐，浮顶与罐壁之间应采用浸液式密封、机械式鞋形密封等高效密封方式；对于外浮顶罐，浮顶与罐壁之间应采用双重密封，且一次密封应采用浸液式密封、机械式鞋形密封等高效密封方式。 b）采用固定顶罐，排放的废气应收集处理并满足相关行业排放标准的要求（无行业排放标准的应满足GB 16297的要求），或者处理效率不低于90%。 c）采用气相平衡系统。 d）采取其他等效措施。 5.2.3 储罐运行维护要求 5.2.3.1 浮顶罐 a）浮顶罐罐体应保持完好，不应有孔洞、缝隙。浮顶边缘密封不应有破损。 b）储罐附件开口（孔），除采样、计量、例行检查、维护和其他正常活动外，应密闭。 c）支柱、导向装置等储罐附件穿过浮顶时，应采取密封措施。 d）除储罐排空作业外，浮顶应始终漂浮于储存物料的表面。 e）自动通气阀在浮顶处于漂浮状态时应关闭且密封良好，仅在浮顶处于支撑状态时开启。 f）边缘呼吸阀在浮顶处于漂浮状态时应密封良好，并定期检查定压是否符合设定要求。 g）除自动通气阀、边缘呼吸阀外，浮顶的外边缘板及所有通过浮顶的开孔接管均应浸入液面下。 5.2.3.2 固定顶罐 a）固定顶罐罐体应保持完好，不应有孔洞、缝隙。 b）储罐附件开口（孔），除采样、计量、例行检查、维护和其他正常活动外，应密闭。 c）定期检查呼吸阀的定压是否符合设定要求。 5.2.3.3 维护与记录 挥发性有机液体储罐若不符合5.2.3.1条或5.2.3.2条规定，应记录并在90 d内修复或排空储罐停止使用。如延迟修复或排空储罐，应将相关方案报生态环境主管部门确定。 6 VOCs物料转移和输送无组织排放控制要求 6.1 基本要求 6.1.1 液态VOCs物料应采用密闭管道输送。采用非管道输送方式转移液态VOCs物料时，应采用密闭容器、罐车。 6.1.2 粉状、粒状VOCs物料应采用气力输送设备、管状带式输送机、螺旋输送机等密闭输送方式，或者采用密闭的包装袋、容器或罐车进行物料转移。 6.1.3 对挥发性有机液体进行装载时，应符合6.2条规定。 6.2 挥发性有机液体装载 6.2.1 装载方式 挥发性有机液体应采用底部装载方式；若采用顶部浸没式装载，出料管口距离槽（罐）底部高度应小于200 mm。 6.2.2 装载控制要求 装载物料真实蒸气压≥27.6 kPa且单一装载设施的年装载量≥500 m3的，装载过程应符合下列规定之一： a）排放的废气应收集处理并满足相关行业排放标准的要求（无行业排放标准的应满足GB 16297的要求），或者处理效率不低于80%； b）排放的废气连接至气相平衡系统。 6.2.3 装载特别控制要求 装载物料真实蒸气压≥27.6 kPa且单一装载设施的年装载量≥500 m3，以及装载物料真实蒸气压≥5.2 kPa但＜27.6 kPa且单一装载设施的年装载量≥2500 m3的，装载过程应符合下列规定之一： a）排放的废气应收集处理并满足相关行业排放标准的要求（无行业排放标准的应满足GB 16297的要求），或者处理效率不低于90%； b）排放的废气连接至气相平衡系统。 7 工艺过程VOCs无组织排放控制要求 7.1 涉VOCs物料的化工生产过程 7.1.1 物料投加和卸放 a）液态VOCs物料应采用密闭管道输送方式或采用高位槽（罐）、桶泵等给料方式密闭投加。无法密闭投加的，应在密闭空间内操作，或进行局部气体收集，废气应排至VOCs废气收集处理系统。 b）粉状、粒状VOCs物料应采用气力输送方式或采用密闭固体投料器等给料方式密闭投加。无法密闭投加的，应在密闭空间内操作，或进行局部气体收集，废气应排至除尘设施、VOCs废气收集处理系统。 c）VOCs物料卸（出、放）料过程应密闭，卸料废气应排至VOCs废气收集处理系统；无法密闭的，应采取局部气体收集措施，废气应排至VOCs废气收集处理系统。 7.1.2 化学反应 a）反应设备进料置换废气、挥发排气、反应尾气等应排至VOCs废气收集处理系统。 b）在反应期间，反应设备的进料口、出料口、检修口、搅拌口、观察孔等开口（孔）在不操作时应保持密闭。 7.1.3 分离精制 a）离心、过滤单元操作应采用密闭式离心机、压滤机等设备，离心、过滤废气应排至VOCs废气收集处理系统。未采用密闭设备的，应在密闭空间内操作，或进行局部气体收集，废气应排至VOCs废气收集处理系统。 b）干燥单元操作应采用密闭干燥设备，干燥废气应排至VOCs废气收集处理系统。未采用密闭设备的，应在密闭空间内操作，或进行局部气体收集，废气应排至VOCs废气收集处理系统。 c）吸收、洗涤、蒸馏/精馏、萃取、结晶等单元操作排放的废气，冷凝单元操作排放的不凝尾气，吸附单元操作的脱附尾气等应排至VOCs废气收集处理系统。 d）分离精制后的VOCs母液应密闭收集，母液储槽（罐）产生的废气应排至VOCs废气收集处理系统。 7.1.4 真空系统 真空系统应采用干式真空泵，真空排气应排至VOCs废气收集处理系统。若使用液环（水环）真空泵、水（水蒸气）喷射真空泵等，工作介质的循环槽（罐）应密闭，真空排气、循环槽（罐）排气应排至VOCs废气收集处理系统。 7.1.5 配料加工和含VOCs产品的包装 VOCs物料混合、搅拌、研磨、造粒、切片、压块等配料加工过程，以及含VOCs产品的包装（灌装、分装）过程应采用密闭设备或在密闭空间内操作，废气应排至VOCs废气收集处理系统；无法密闭的，应采取局部气体收集措施，废气应排至VOCs废气收集处理系统。 7.2 含VOCs产品的使用过程 7.2.1 VOCs质量占比大于等于10%的含VOCs产品，其使用过程应采用密闭设备或在密闭空间内操作，废气应排至VOCs废气收集处理系统；无法密闭的，应采取局部气体收集措施，废气应排至VOCs废气收集处理系统。含VOCs产品的使用过程包括但不限于以下作业： a）调配（混合、搅拌等）； b）涂装（喷涂、浸涂、淋涂、辊涂、刷涂、涂布等）； c）印刷（平版、凸版、凹版、孔版等）； d）粘结（涂胶、热压、复合、贴合等）； e）印染（染色、印花、定型等）； f）干燥（烘干、风干、晾干等）； g）清洗（浸洗、喷洗、淋洗、冲洗、擦洗等）。 7.2.2 有机聚合物产品用于制品生产的过程，在混合/混炼、塑炼/塑化/熔化、加工成型（挤出、注射、压制、压延、发泡、纺丝等）等作业中应采用密闭设备或在密闭空间内操作，废气应排至VOCs废气收集处理系统；无法密闭的，应采取局部气体收集措施，废气应排至VOCs废气收集处理系统。