标准编号:	DB 32/3151-2016
中文名称:	化学工业挥发性有机物排放标准
英文名称:	Emission standard of volatile organic compounds for chemical industry
行业分类:	DB    地方标准
发布机构:	江苏省环境保护厅;江苏省质量技术监督局
发布日期:	2017-1-10
实施日期:	2017-2-1
标准状态:	valid
翻译语言:	英文
文件格式:	PDF
中文字符数:	10000 字
翻译价格(元):	1000.0
交付时间:	付款后 1 个工作日

Codeofchina.com is in charge of this English translation. In case of any doubt about the English translation, the Chinese original shall be considered authoritative. This standard is formulated to implement the laws and regulations such as Environmental Protection Law of the People's Republic of China, Law of the People's Republic of China on the Prevention and Control of Atmospheric Pollution and Regulation of Jiangsu Province on the Prevention and Control of Atmospheric Pollution, control the emission of volatile organic compounds for chemical industry, improve the environmental air quality, protect human health and ecological environment, and promote the technological progress and sustainable development of chemical industry. This standard specifies the requirements for emission control, monitoring and supervision of volatile organic compounds in chemical industry facilities or production equipment. This standard is the basic requirement for emission control of volatile organic compounds in chemical industry facilities or production equipment. Relevant national or local pollutant emission standards are applicable to the air pollutants, water pollutants and environmental noises not specified in this standard, and relevant national or local solid waste pollution control standards are applicable to the identification, treatment and disposal of generated solid wastes. This standard is issued for the first time. In case of any relevant standards issued by the State or Jiangsu province stricter than this standard after the implementation date hereof, such standards shall prevail. When the requirements of environmental impact assessment documents or pollution emission permit are stricter than those in this standard, the approved environmental impact assessment documents or pollution emission permit shall prevail. This standard is developed in accordance with the rules given in GB/T 1.1-2009. For the purposes of this standard, Annexes A and B are normative and Annex C is informative. This standard is organized and formulated by the Environmental Protection Bureau of Jiangsu Province. This standard was drafted by Jiangsu Provincial Academy of Environmental Science. This standard was approved by Jiangsu Provincial People's Government on December 9, 2016. This standard shall be implemented from February 1, 2017. The Environmental Protection Bureau of Jiangsu Province is responsible for the explanation of this standard. Emission standard of volatile organic compounds for chemical industry 1 Application scope This standard specifies the requirements for emission control, monitoring and supervision of volatile organic compounds (hereinafter referred to as VOCs) in chemical industry facilities (2614 organic chemical raw material manufacturing, 2625 organic fertilizer and microbial fertilizer manufacturing, 263 pesticide manufacturing, 264 coating/printing ink/pigment and similar product manufacturing, 266 special chemical product manufacturing, 268 daily chemical product manufacturing, 271 chemical active pharmaceutical ingredient manufacturing, 272 chemical agent manufacturing, 275 veterinary drugs manufacturing and 276 biopharmaceuticals manufacturing) or production equipment. This standard is applicable to the emission control of VOCs in existing chemical industry facilities or production equipment, as well as the environmental impact assessment, the environmental protection equipment design, the acceptance of environmental protection after completion and the emission control of VOCs after being put into production of new, renovated and extended projects. This standard is applicable to the legal pollutant emission behaviors. The site selection of new pollution sources and the management of existing pollution sources within special protected zone are in accordance with laws, regulations and rules such as Law of the People's Republic of China on Prevention and Control of Water Pollution, Law of the People's Republic of China on the Prevention and Control of Atmospheric Pollution, Marine Environment Protection Law of the People's Republic of China, Law of the People's Republic of China on Prevention of Environmental Pollution Caused by Solid Waste, Law of the People's Republic of China on Environmental Impact Assessment and Regulation of Jiangsu Province on the Prevention and Control of Atmospheric Pollution. 2 Normative references The following documents contain provisions which, through reference in this standard, constitute provisions of this standard. For undated references, the latest edition applies. GB/T 4754 Industrial classification for national economic activities GB 14554 Emission standards for odor pollutants GB/T 14675 Air quality - Determination of odor - Triangle odor bag method GB/T 15501 Air quality - Determination of nitrobenzene (mononitro- and dinitro-compound) - Reduction by zinc-N-(1-Naphthyl) ethylene diamine dihydrochloride spectrophotometric method GB/T 15502 Air quality - Determination of aniline - N-(1-naphthyl) ethylene diamine dihydrochloride spectrophotometric method GB/T 15516 Air quality - Determination of formaldehyde - Acetylacetone spectrophotometric method GB/T 16157 Determination of particulates and sampling methods of gaseous pollutants emitted from exhaust gas of stationary source HJ/T 32 Stationary source emission - Determination of phenols - 4-Amino-antipyrine spectrophotometric method HJ/T 33 Stationary source emission - Determination of methanol - Gas chromatography HJ/T 34 Stationary source emission - Determination of vinyl chloride - Gas chromatography HJ/T 35 Stationary source emission - Determination of acetaldehyde - Gas chromatography HJ/T 36 Stationary source emission - Determination of acrolein - Gas chromatography HJ/T 37 Stationary source emission - Determination of acrylonitrile - Gas chromatography HJ/T 38 Stationary source emission - Determination of nonmethane hydrocarbons - Gas chromatography HJ/T 39 Stationary source emission - Determination of chlorobenzenes - Gas chromatography HJ/T 55 Technical guidelines for fugitive emission monitoring of air pollutants HJ/T 66 Stationary source emission - Determination of chlorobenzenes - Gas chromatography HJ/T 68 Stationary source emission - Determination of exhauster anilines - Gas chromatography HJ/T 194 Technical specifications on manual methods for ambient air quality monitoring HJ/T 373 Technical specifications of quality assurance and quality control for monitoring of stationary pollution source (on trial) HJ/T 397 Technical specifications for emission monitoring of stationary source HJ 583 Ambient air - Determination of benzene and its analogies using sorbent adsorption thermal desorption and gas chromatography HJ 584 Ambient air - Determination of benzene and its analogies by activated charcoal adsorption carbon disulfide desorption and gas chromatography HJ 638 Ambient air - Determination of phenolic compounds by high performance liquid chromatography HJ 644 Ambient Air - Determination of volatile organic compounds - Activated charcoal adsorption carbon disulfide desorption/gas chromatographic method HJ 645 Ambient Air - Determination of volatile halogenated hydrocarbons - Activated charcoal adsorption and carbon disulfide desorption/gas chromatographic method HJ 683 Ambient air - Determination of aldehyde and ketone compounds - High performance liquid chromatography HJ 732 Emission from stationary sources - Sampling of volatile organic compounds - Bags method HJ 734 Stationary source emission - Determination of volatile organic compounds - Sorbent adsorption and thermal desorption gas chromatography mass spectrometry method HJ 738 Ambient air - Determination of nitroaromatics - Gas chromatography HJ 739 Ambient air - Determination of nitroaromatics - Gas chromatography mass spectrometry HJ 759 Ambient air - Determination of volatile organic compounds - Collected by specially-prepared canisters and analyzed by gas chromatography/mass spectrometry HJ 801 Ambient air and waste gas - Determination of amide compounds - Liquid chromatography Measures for Automatic Monitoring and Management of Pollution Sources (Decree No.28 of the Ministry of Ecology and Environment of the People's Republic of China) Measures for the Administration of Environmental Monitoring (Decree No.39 of the Ministry of Ecology and Environment of the People's Republic of China) Technical Guidelines for Leak Detection and Repair (LDAR) of Jiangsu Province (Trial) (SUHUANBAN [2013] No.318) Technical Specification for Waste Gas Treatment for Chemical Industry of Jiangsu Province (SUHUANBAN [2014] No.3) Guidelines for Leak Detection and Repair in Petrochemical Enterprises (HUANBAN [2015] No.104) Technical Guidelines for Fugitive Emission Control of Volatile Organic Compounds for Chemical Industry of Jiangsu Province (SUHUANBAN [2016] No.95) 3 Terms and definitions For the purposes of this standard, the following terms and definitions apply. 3.1 chemistry industry chemical industry hereof covering 2614 organic chemical raw material manufacturing, 2625 organic fertilizer and microbial fertilizer manufacturing, 263 pesticide manufacturing, 264 coating/printing ink/pigment and similar product manufacturing, 266 special chemical product manufacturing, 268 daily chemical product manufacturing, 271 chemical active pharmaceutical ingredient manufacturing, 272 chemical agent manufacturing, 275 veterinary drugs manufacturing and 276 biopharmaceuticals manufacturing in accordance with GB/T 4754 3.2 standard state state where the temperature is 273.15K and the pressure is 101,325Pa. Standard values specified hereof are benchmarked against the dry gas under standard state 3.3 existing facility chemical industry facilities or production equipment which have been completed and put into operation or whose environmental impact assessment documents have been approved before the implementation date of this standard 3.4 new facility new, renovated and extended projects of chemical industry whose environmental impact assessment documents are approved from the implementation date of this standard 3.5 volatile organic compounds (VOCs) organic compounds involved in photochemical reaction in atmosphere or those determined via measurement or calculation according to specified method 3.6 non-methane hydrocarbon (NMHC) total amount (measured by carbon) of hydrocarbon compounds (except methane) and derivatives to which the detector has an obvious response by adopting the specified monitoring method, which is adopted as the integrated control index for the volatile organic compound emission of stack and enterprise boundary in this standard 3.7 odor concentration dilution ratio necessary for diluting the foul gas (including peculiar smell) with odorless air till the gas is odorless exactly 3.8 emission height of stack height from the ground level of the stack (or its main building structure) to the outlet of the stack, m 3.9 initial emission quantity emission quantity of VOCs not purified per unit time (in hour), kg/h 3.10 maximum acceptable emission concentration upper limit of average concentration of VOCs in stack in any hour, mg/m3 3.11 maximum acceptable emission rate upper limit of mass of pollutants emitted in any hour by an stack with certain emission height, kg/h 3.12 enterprise boundary legal boundary of a production facility, or actual land boundary where legal boundary is unavailable 3.13 boundary VOCs reference point boundary reference point determined in accordance with HJ/T 55; according to VOCs emission and diffusion rules, when the sampling points for monitoring cannot be arranged according to the above requirements due to the conditions, the sampling points for monitoring may also be arranged within but close to the enterprise boundary 3.14 concentration limit at boundary VOCs reference point upper limit of the average concentration at boundary VOCs reference point under standard state in any hour, mg/m3 4 Emission control requirements 4.1 Organized emission limits 4.1.1 The emission limits of VOCs and odor concentration specified in Table 1 shall be implemented for the existing facility from February 1, 2019. 4.1.2 The emission limits of VOCs and odor concentration specified in Table 1 shall be implemented for the new facility from the implementation date of this standard.

Foreword i 1 Application scope 2 Normative references 3 Terms and definitions 4 Emission control requirements 5 Monitoring requirements 6 Implementation and supervision Annex A (Normative) Interpolation method and extrapolation method for determining the maximum acceptable emission rate of stack Annex B (Normative) Calculation method of parameters relevant to stacks Annex C (Informative) Basic requirements for facilities to establish VOCs emission and control accounts

化学工业挥发性有机物排放标准 1 适用范围 本标准规定了化学工业企业（2614有机化学原料制造、2625有机肥料及微生物肥料制造、263农药制造、264涂料/油墨/颜料及类似产品制造、266专用化学产品制造、268日用化学产品制造、271化学药品原料药制造、272化学药品制剂制造、275兽用药品制造、276生物药品制造）或生产设施的挥发性有机物排放控制、监测及监督实施要求。 本标准适用于现有化学工业企业或生产设施的挥发性有机物排放控制，以及新、改、扩建项目的环境影响评价、环境保护设施设计、竣工环境保护验收及其投产后的挥发性有机物排放控制。 本标准适用于法律允许的污染物排放行为。新设立污染源的选址和特殊保护区域内现有污染源的管理，按照《中华人民共和国水污染防治法》、《中华人民共和国大气污染防治法》、《中华人民共和国海洋环境保护法》、《中华人民共和国固体废物污染环境防治法》、《中华人民共和国环境影响评价法》、 《江苏省大气污染防治条例》等法律、法规和规章的相关规定执行。 2 规范性引用文件 本标准内容引用了下列文件或其中的条款。凡是不注明日期的引用文件，其有效版本适用于本标准。 GB/T 4754 国民经济行业分类 GB 14554 恶臭污染物排放标准 GB/T 14675 空气质量 恶臭的测定 三点比较式臭袋法 GB/T 15501 空气质量 硝基苯类（一硝基和二硝基化合物）的测定 锌还原-盐酸萘乙二胺分光光度法 GB/T 15502 空气质量 苯胺类的测定 盐酸萘乙二胺分光光度法 GB/T 15516 空气质量 甲醛的测定 乙酰丙酮分光光度法 GB/T 16157 固定污染源排气中颗粒物测定与气态污染物采样方法 HJ/T 32 固定污染源排气中酚类化合物的测定 4-氨基安替比林分光光度法HJ/T 33 固定污染源排气中甲醇的测定 气相色谱法 HJ/T 34 固定污染源排气中氯乙烯的测定 气相色谱法HJ/T 35 固定污染源排气中乙醛的测定 气相色谱法HJ/T 36 固定污染源排气中丙烯醛的测定 气相色谱法HJ/T 37 固定污染源排气中丙烯腈的测定 气相色谱法 HJ/T 38 固定污染源排气中非甲烷总烃的测定 气相色谱法HJ/T 39 固定污染源排气中氯苯类的测定 气 相 色 谱 法 HJ/T 55 大气污染物无组织排放监测技术导则 HJ/T 66 大气固定污染源 氯苯类化合物的测定 气相色谱法 HJ/T 68 大气固定污染源 苯胺类的测定 气相色谱法 HJ/T 194 环境空气质量手工监测技术规范 HJ/T 373 固定污染源监测质量保证与质量控制技术规范（试行） HJ/T 397 固定源废气监测技术规范 HJ 583 环境空气 苯系物的测定 固体吸附/热脱附-气相色谱法 HJ 584 环境空气 苯系物的测定 活性炭吸附/二硫化碳解吸-气相色谱法 HJ 638 环境空气 酚类化合物的测定 高效液相色谱法 HJ 644 环境空气 挥发性有机物的测定 吸附管采样-热脱附/气相色谱-质谱法HJ 645 环境空气 挥发性卤代烃的测定 活性炭吸附-二硫化碳解吸/气相色谱法HJ 683 环境空气 醛、酮类化合物的测定 高效液相色谱法 HJ 732 固定污染源废气 挥发性有机物的采样 气袋法 HJ 734 固定污染源废气 挥发性有机物的测定 固相吸附-热脱附/气相色谱-质谱法 HJ 738 环境空气 硝基苯类化合物的测定 气相色谱法 HJ 739 环境空气 硝基苯类化合物的测定 气相色谱-质谱法 HJ 759 环境空气 挥发性有机物的测定 罐采样/气相色谱-质谱法 HJ 801 环境空气和废气 酰胺类化合物的测定 液相色谱法 《污染源自动监控管理办法》（国家环境保护总局令第28号） 《环境监测管理办法》（国家环境保护总局令第39号） 《江苏省泄漏检测与维修（LDAR）实施技术指南（试行）》（苏环办[2013]318号） 《江苏省化工行业废气治理技术规范》（苏环办[2014]3号） 《石化企业泄漏检测与修复工作指南》（环办[2015]104号） 《江苏省化学工业挥发性有机物无组织排放控制技术指南》（苏环办[2016]95号） 3 术语和定义 下列术语和定义适用于本标准。 3.1 3.1 化学工业 chemical industry 根据GB/T 4754，本标准所指化学工业包括：2614有机化学原料制造、2625有机肥料及微生物肥料制造、263农药制造、264涂料/油墨/颜料及类似产品制造、266专用化学产品制造、268日用化学产品制造、271化学药品原料药制造、272化学药品制剂制造、275兽用药品制造、276生物药品制造。 3.2 3.2 标准状态 standard state 温度为273.15 K，压力为101325 Pa时的状态，简称“标态”。本标准规定的各项标准值，均以标准状态下的干气体为基准。 3.3 3.3 现有企业 existing facility 本标准实施之日前已建成投产或环境影响评价文件已通过审批的化学工业企业或生产设施。 3.4 3.4 新建企业 new facility 自本标准实施之日起环境影响评价文件通过审批的新建、改建和扩建化学工业建设项目。 挥发性有机物 volatile organic compounds（VOCs） 参与大气光化学反应的有机化合物，或者根据规定的方法测量或核算确定的有机化合物。 3.6 非甲烷总烃 non-methane hydrocarbon（NMHC） 采用规定的监测方法，检测器有明显响应的除甲烷外的碳氢化合物及衍生物的总量（以碳计）。本标准使用“非甲烷总烃（NMHC）”作为排气筒和厂界挥发性有机物排放的综合性控制指标。 3.7 臭气浓度 odor concentration 恶臭气体（包括异味）用无臭空气进行稀释，稀释到刚好无臭时，所需稀释倍数。 3.8 排气筒高度 emission height of stack 自排气筒（或其主体建筑构造）所在的地平面至排气筒出口计的高度，单位为m。 3.9 初始排放量 initial emission quantity 单位时间内（以小时计），挥发性有机物未经净化处理的排放量，单位为kg/h。 3.10 最高允许排放浓度 maximum acceptable emission concentration 排气筒中挥发性有机物任何一小时浓度平均值不得超过的限值，单位为mg/m3。 3.11 最高允许排放速率 maximum acceptable emission rate 一定高度的排气筒任何一小时所排放污染物的质量不得超过的限值，单位为kg/h。 3.12 厂界 enterprise boundary 生产企业的法定边界。若无法定边界，则指实际占地边界。 3.13 厂界挥发性有机物监控点 boundary VOCs reference point 按照HJ/T 55确定的厂界监控点，根据挥发性有机物的排放、扩散规律，当受条件限制，无法按上述要求布设监测采样点时，也可将监测采样点设于工厂厂界内侧靠近厂界的位置。 3.14 厂界挥发性有机物监控点浓度限值 concentration limit at boundary VOCs reference point 标准状态下厂界挥发性有机物监控点的挥发性有机物浓度在任何一小时的平均值不得超过的值，单位为mg/m3。 4 排放控制要求 4.1 有组织排放限值 4.1.1 现有企业自 2019 年 2 月 1 日起执行表 1 规定的挥发性有机物及臭气浓度排放限值。 4.1.2 新建企业自本标准实施之日起执行表 1 规定的挥发性有机物及臭气浓度排放限值。 表1 挥发性有机物及臭气浓度排放限值 序号 污染物项目 最高允许排放浓度（mg/m3）d 与排气筒高度对应的最高允许排放速率（kg/h）e 15m 20m 30m 40m 50m 1 氯甲烷 a 20 1.1 2.2 5.6 10 16 2 二氯甲烷 a 50 0.54 1.1 2.9 5.2 8.1 3 三氯甲烷 a 20 0.54 1.1 2.9 5.2 8.1 4 1,2-二氯乙烷 a 7.0 0.54 1.1 2.9 5.2 8.1 5 环氧乙烷 a 5.0 0.15 0.29 0.77 1.4 2.2 6 1,2-环氧丙烷 a 5.0 0.43 0.86 2.3 4.2 6.5 7 环氧氯丙烷 a 5.0 0.54 1.1 2.9 5.2 8.1 8 氯乙烯 10 0.54 1.1 2.9 5.2 8.1 9 三氯乙烯 a 30 0.72 1.5 3.8 7.0 11 10 1,3-丁二烯 a 5.0 0.36 0.72 1.9 3.5 5.4 11 苯 6.0 0.36 0.72 1.9 3.5 5.4 12 甲苯 25 2.2 4.3 12 21 32 13 二甲苯 40 0.72 1.5 3.8 7.0 11 14 氯苯类 20 0.36 0.72 1.9 3.5 5.4 15 酚类 20 0.07 0.14 0.38 0.70 1.1 16 苯乙烯 20 0.54 1.1 2.9 5.2 8.1 17 硝基苯类 12 0.04 0.07 0.19 0.35 0.54 18 苯胺类 20 0.36 0.72 1.9 3.5 5.4 19 甲醇 60 3.6 7.2 19 35 54 20 正丁醇 a 40 0.36 0.72 1.9 3.5 5.4 21 丙酮 40 1.3 2.5 6.7 12 19 22 甲醛 10 0.18 0.36 1.0 1.7 2.7 23 乙醛 20 0.04 0.07 0.19 0.35 0.54 24 丙烯腈 5.0 0.18 0.36 1.0 1.7 2.7 25 丙烯醛 10 0.36 0.72 1.9 3.5 5.4 26 丙烯酸 a 20 0.9 1.8 4.8 8.7 14 27 丙烯酸酯类 a，b 20 0.11 0.22 0.58 1.0 1.6 28 丙烯酰胺 5.0 0.15 0.29 0.77 1.4 2.2 29 乙酸乙烯酯 a 20 0.54 1.1 2.9 5.2 8.1 30 乙酸酯类 c 50 1.1 2.2 5.6 10 16 31 乙腈 a 30 1.1 2.2 5.6 10 16 32 吡啶 a 4.0 0.29 0.58 1.5 2.8 4.3 33 N,N-二甲基甲酰胺 30 0.54 1.1 2.9 5.2 8.1 34 非甲烷总烃 80 7.2 14 38 70 108 35 臭气浓度 1500（无量纲） — — — — — 注：a 待国家污染物监测方法标准发布后实施。 b 丙烯酸酯类排放限值指丙烯酸甲酯、丙烯酸乙酯、丙烯酸丁酯的排放限值的数学加和。 c 乙酸酯类排放限值指乙酸乙酯、乙酸丁酯的排放限值的数学加和。 d 当排气筒高度＜15m 时，最高允许排放浓度按表 2 厂界挥发性有机物监控点浓度限值 5 倍执行。 e 当排气筒高度＞50m 时，执行排气筒高度为 50m 所对应的最高允许排放速率。 4.2 厂界挥发性有机物监控点浓度限值 4.2.1 现有企业自 2019 年 2 月 1 日起执行表 2 规定的厂界挥发性有机物监控点浓度限值和臭气浓度限值。 4.2.2 新建企业自本标准实施之日起执行表 2 规定的厂界挥发性有机物监控点浓度限值和臭气浓度限值。 表2 厂界挥发性有机物监控点浓度限值和臭气浓度限值 序号 污染物项目 厂界监控点浓度限值（mg/m3） 序号 污染物项目 厂界监控点浓度限值（mg/m3） 1 氯甲烷 1.2 19 甲醇 1.0 2 二氯甲烷 4.0 20 正丁醇 a 0.50 3 三氯甲烷 0.40 21 丙酮 0.80 4 1,2-二氯乙烷 0.14 22 甲醛 0.05 5 环氧乙烷 a 0.04 23 乙醛 0.01 6 1,2-环氧丙烷 a 0.10 24 丙烯腈 0.15 7 环氧氯丙烷 a 0.02 25 丙烯醛 0.10 8 氯乙烯 0.30 26 丙烯酸 a 0.25 9 三氯乙烯 0.60 27 丙烯酸酯类 a，b 1.0 10 1,3-丁二烯 0.10 28 丙烯酰胺 0.10 11 苯 0.12 29 乙酸酯类 c 4.0 12 甲苯 0.60 30 乙酸乙烯酯 0.20 13 二甲苯 0.30 31 乙腈 a 0.60 14 氯苯类 0.20 32 吡啶 a 0.08 15 酚类 0.02 33 N,N-二甲基甲酰胺 0.40 16 苯乙烯 0.50 34 非甲烷总烃 4.0 17 硝基苯类 0.01 35 臭气浓度 20（无量纲） 18 苯胺类 0.20 — — — 4.3 排气筒高度与排放速率 4.3.1 排气筒高度原则上不应低于 15 m，若低于 15 m，其最高允许排放速率标准值按附录 A 外推法计算结果再严格 50%执行。 4.3.2 排气筒高度处于表 1 所列的两个排气筒高度之间时，其最高允许排放速率标准值按附录 A 内插法计算结果执行。 4.3.3 企业内部有多根排放同一种污染物的排气筒时，若两根排气筒距离小于其几何高度之和，应合并视为一根等效排气筒。若有三根以上的近距离排气筒，且排放同一种污染物，应以前两根的等效排气筒， 依次与第三、第四根排气筒取等效值。等效排气筒有关参数计算方法参见附录 B。 4.3.4 排气筒高度除须遵守表列排放速率标准值外，还应高出周围 200 m 半径范围内的建筑物 5 m 以上，不能达到该项要求的排气筒，应按其高度对应的表列排放速率标准值严格 50%执行或根据 4.3.2 和 4.3.3 条确定排放速率标准值再严格 50%执行。 4.4 污染控制要求 4.4.1 现有企业自 2019 年 2 月 1 日起，新建企业自本标准实施之日起，执行本节的工艺控制要求。 4.4.2 企业应按照《江苏省化学工业挥发性有机物无组织排放控制技术指南》、《江苏省化工行业废气治理技术规范》等，控制储存和装卸过程、工艺操作过程、废水集输处理和固废（液）贮存过程、生产设备密封点泄漏、开停工及检维修等非正常工况产生的含 VOCs 废气排放。 4.4.3 产生挥发性有机物的生产工艺和装置应设立局部或整体气体收集系统和净化处理装置实现达标排放。 4.4.4 易产生挥发性有机物泄漏的企业应按照《石化企业泄漏检测与修复工作指南》、《江苏省泄漏检测与维修（LDAR）实施技术指南（试行）》等落实泄漏检测与修复工作。 4.4.5 企业应按照附录 C 建立污染物排放控制台账，并保存相关记录。VOCs 废气处理装置应设置运行或排放等有效监控系统，并按照附录 C 的要求保存记录，至少三年。 4.4.6 挥发性有机物排放集中的区域，或大气环境容量较小、容易发生严重大气环境污染问题而需要采取特别保护措施的区域，应根据批复的环境影响评价文件或者环境保护主管部门的要求在其边界设置监控点。 5 监测要求 5.1 一般要求 5.1.1 按照有关法律和《环境监测管理办法》等规定，污染物责任主体应建立监测制度，制定监测方案， 对污染物排放状况开展自行监测。必要时，根据环境保护主管部门的要求，对周边环境质量的影响开展自行监测，保存原始监测记录，并公布监测结果。