标准编号:	GB/T 21181-2017
中文名称:	再生铅及铅合金锭
英文名称:	Secondarily lead and lead alloy ingots
中标分类:	H69    再生有色金属及其合金
行业分类:	GB    国家标准
ICS分类:	77.150.60 77.150.60    铅、锌和锡产品 77.150.60
发布机构:	中华人民共和国国家质量监督检验检疫总局 中国国家标准化管理委员会
发布日期:	2017-07-12
实施日期:	2018-6-1
标准状态:	valid
替代旧标准:	GB/T 21181-2007 再生铅及铅合金锭
翻译语言:	英文
文件格式:	PDF
中文字符数:	11000 字
翻译价格(元):	290.0
交付时间:	付款后 1 个工作日

Codeofchina.com is in charge of this English translation. In case of any doubt about the English translation, the Chinese original shall be considered authoritative. This standard is developed in accordance with the rules given in GB/T 1.1-2009. This standard replaces GB/T 21181-2007 Secondarily lead and lead alloy ingots. The following technical content changes have been made with respect to GB/T 21181-2007: ——Three designations ZSPb99.98, ZSPb99.95 and ZSPb98.00 are canceled; ——Two designations ZSPb99.994 and ZSPb99.992 are added. This standard was proposed by the China Nonferrous Metals Industry Association. This standard was prepared by National Technical Committee on Nonferrous Metals of Standardization Administration of China (SAC/TC 243). Secondarily lead and lead alloy ingots 1 Scope This standard specifies the requirements, test methods, inspection rules, marking, packaging, transportation, storage, quality certificate and order form (or contract) contents of secondarily lead and lead alloy ingots. This standard is applicable to secondarily lead and its alloy ingots produced by smelting and processing waste materials containing lead, which are mainly used in the fields of batteries, alloys and chemical industry. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. GB/T 1250 Rules for expression and judgment of limiting values GB/T 4103 Methods for chemical analysis of lead and lead alloys (all parts) GB/T 8170 Rules of rounding off for numerical values & expression and judgment of limiting values 3 Requirements 3.1 Classification Secondarily lead and lead alloy ingots are classified into seven designations according to their chemical composition: ZSPB99.994, ZSPB99.992, ZSPBSbl, ZSPBSb2, ZSPBCa, ZSPBSnl and ZSPBSn2. 3.2 Chemical composition 3.2.1 The chemical composition of secondarily lead and lead alloy ingots shall comply with the provisions in Table 1. 3.2.2 The special requirements, if any, proposed by the buyer for alloying elements and impurities shall be determined by the supplier and the buyer through negotiation. 3.2.3 Lead (Pb) content is 100% minus the sum of the other elements actually measured in Table 1. 3.3 Physical specifications 3.3.1 Secondarily lead and lead alloy ingots are rectangular trapezoids with bundling grooves at the bottom and protruding ears at both ends. 3.3.2 The weight per ingot may be 48 kg+2 kg, 40 kg+2 kg, 24 kg+1 kg, or determined by negotiation between the supplier and the buyer. 3.3.3 If the buyer raises special requirements on the specifications and shapes of secondarily lead and lead alloy ingots, agreement made reached through negotiation of the supplier and the buyer. 3.3.4 The surface of secondarily lead and lead alloy ingots shall be free from slag, karst cave, granular oxide, inclusions and external pollution, cold segregation, and flash burr greater than 10 mm (trimming is allowed). 4 Test methods 4.1 The analytical method for chemical composition arbitration of secondarily lead and lead alloy ingots shall be in accordance with GB/T 4103 (all parts), or follow the method approved by both parties. 4.2 The surface quality of secondarily lead and lead alloy ingots shall be inspected visually. Table 1 Chemical composition of secondarily lead and lead alloy ingots Category Designation Chemical composition/% Main components Impurity content, ≤ Pb Sb Ca Sn Al Ag Cu Bi As Sb Sn Zn Fe Cd Ni Total impurity Secondarily lead ZSPb99.994 ≥99.994 - - - - 0.0008 0.0004 0.003 0.0002 0.0005 0.0003 0.0002 0.0002 - - 0.006 ZSPb99.992 ≥99.992 - - - - 0.001 0.0004 0.004 0.0004 0.0005 0.0004 0.0004 0.0004 0.0002 0.0002 0.008 Secondarily lead alloy ingots Lead-antimony alloy ZSPbSb1 Balance 1.5 to 3.5 0.10 to 0.25 - 0.01 0.03 0.02 0.01 - - 0.001 0.001 0.001 0.001 - ZSPbSb2 Balance 3.6 to 7.5 0.26 to 0.50 - 0.02 0.05 0.03 0.02 - - 0.001 0.001 0.001 0.001 - Lead-calcium alloy ZSPbCa Balance - 0.06 to 0.12 0.05 to 1.80 0.01 to 0.04 0.001 0.002 0.008 0.001 0.005 - 0.001 0.001 0.001 0.001 - Lead-tin alloy ZSPbSn1 Balance - - 1.5 to 3.5 - - 0.03 0.03 0.03 0.1 - 0.002 0.02 - - - ZSPbSn2 Balance - - 3.6 to 7.5 - - 0.03 0.03 0.03 0.1 - 0.002 0.02 - - - Note: Designation representation: "ZS" is the initials of "regeneration" in Chinese Pinyin. 5 Inspection rules 5.1 Inspection and acceptance 5.1.1 Secondarily lead and lead alloy ingots shall be inspected by the supplier's technical supervision department to ensure that the product quality meets the requirements of this standard or the order form (or contract), with the quality certificate filled in. 5.1.2 The buyer shall inspect the products received according to the provisions of this standard. If the inspection results are inconsistent with the provisions of this standard or the order form (or contract), the buyer shall submit them to the supplier within 15 days from the date of receiving the products, and the supplier and the buyer shall negotiate and solve them. In case of arbitration, arbitration sampling shall be conducted jointly by both suppliers and buyer at the buyer's site. 5.2 Batching 5.2.1 Secondarily lead and lead alloy ingots shall be submitted for inspection in batches, each batch shall consist of products of the same smelting number, and the batch size shall not exceed 120 to 5.2.2 According to the requirements of the buyer, it is allowed to form one inspection batch by multiple production batches of the same designation, and the batch size shall be executed according to the requirements of the buyer. 5.3 Inspection items Each batch of secondarily lead and lead alloy ingots shall be inspected for chemical composition and surface quality. 5.4 Arbitration sampling and sample preparation 5.4.1 Arbitration sampling quantity: 2% of secondarily lead and lead alloy ingots shall be randomly selected as sample ingots, and the total number of sample ingots shall be multiples of 6 for grouping. If there are less than 6 ingots after grouping, they shall be supplemented from secondarily lead and lead alloy ingots, but shall not be discarded. 5.4.2 Arbitration sampling method: Ingots shall be sampled in groups of 6 ingots. Sampling shall be conducted by drilling or sawing. At drilling or sawing, no lubricant shall be used, and the speed shall not oxidize the sample. At sampling, the skin shall be removed, and the depth of drilling and sawing shall not be less than two-thirds of the ingot thickness. To specific: a) Drilling method: Sample with a drill bit with a diameter of 10 mm to 15 mm, arrange the pouring surface A and the bottom surface B into a rectangle in turn, draw two diagonal lines on the rectangle, with the two points intersecting the longitudinal center line of each ingot being the sampling points of the ingot, as shown in Figure 1. b) Sawing method: The saw blade is perpendicular to the regenerated lead and lead alloy ingot, and sawing shall be conducted transversely through the sampling point of drilling method. 5.4.3 Preparation of sample: Make the obtained sample into chip shape of not more than 4 mm, remove the iron filings brought in during processing with magnets, mix carefully and shrink it to not less than 360 g by quartering method, and make it serve as arbitration analysis sample.

Foreword i 1 Scope 2 Normative references 3 Requirements 4 Test methods 5 Inspection rules 6 Marking, packaging, storage, transportation and quality certificate 7 Contents of order form (or contract)

ICS 77.150.60 H69 中华人民共和国国家标准 GB/T 21181—2017 代替 GB/T 21181—2007 再生铅及铅合金锭 Secondarily lead and lead alloy ingots 2022-06-30发布 2023-06-30实施 中华人民共和国国家质量监督检验检疫总局 中国国家标准化管理委员会 发布 GB/T 21181—2017 前言 本标准按照GB/T 1.1-2009给出的规则起草。 本标准代替GB/T 21181—2007《再生铅及铅合金锭》，与GB/T 21181-2007相比，主要技术内容 变化如下： 一取消 ZSPb99.98、ZSPb99.95、ZSPb98.00 三个牌号； 一增加 ZSPb99.994,ZSPb99.992 两个牌号。 本标准由中国有色金属工业协会提出。 本标准由全国有色金属标准化技术委员会(SAC/TC 243)归口。 再生铅及铅合金锭 1范围 本标准规定了再生铅及铅合金锭的要求、试验方法、检验规则及标志、包装、贮存、运输、质量证明书 及订货单（或合同）。 本标准适用于以含铅的废料为原料经冶炼加工生产的再生铅及其合金锭，主要应用于蓄电池、合金 和化工等领域。 2规范性引用文件 下列文件对于本文件的应用是必不可少的。凡是注日期的引用文件，仅注日期的版本适用于本文 件。凡是不注日期的引用文件，其最新版本（包括所有的修改单）适用于本文件。 GB/T 1250极限数值的表示方法和判定方法 GB/T 4103（所有部分）铅及铅合金化学分析方法 GB/T 8170数值修约规则与极限数值的表示和判定 3要求 3.1产品分类 再生铅及铅合金锭按化学成分分为7个牌号:ZSPB99. 994、ZSPb99.992、ZSPbSbl, ZSPbSb2、 ZSPbCa、ZSPbSnl、ZSPbSn2。 3.2化学成分 3.2.1再生铅及铅合金锭的化学成分应符合表1的规定。 3.2.2当需方对合金元素和杂质有特殊要求时，供需双方可以协商确定。 3.2.3铅（Pb）的含量为100%减去实际测得表1中所列其他元素总和的余量。 3.3物理规格 3.3.1再生铅及铅合金锭为长方梯形，底部有打捆凹槽.两端有突出耳部。 3.3.2每锭单重可为48 kg+2 kg,40 kg+2 kg.24 kg+1 kg,或由供需双方协商确定。 3.3.3需方如对再生铅及铅合金锭的规格形状有特殊要求，可由供需双方商定。 3.3.4再生铅及铅合金锭表面不得有熔渣、溶洞、粒状氧化物、夹杂物及外来污染；不得有冷隔，不得有 大于10 mm的飞边毛刺（允许修整）。 4试验方法 4.1再生铅及铅合金锭的化学成分仲裁分析方法按GB/T 4103（所有部分）的规定进行，或按供需双方 认可的分析方法进行。 4.2再生铅及铅合金锭的表面质量用目视法检验。 表1再生铅及铅合金锭化学成分 类别 牌号 化学成分/% 主要成分 杂质含量不大于 Pb Sb Ca Sn Al Ag Cu Bi As Sb Sn Zn Fe Cd Ni 杂质总和 再生铅 ZSPb99.994 ≥99.994 - - - - 0.0008 0.0004 0.003 0.0002 0.0005 0.0003 0.0002 0.0002 - - 0.006 ZSPb99.992 ≥99.992 - - - - 0.001 0.0004 0.004 0.0004 0.0005 0.0004 0.0004 0.0004 0.0002 0.0002 0.008 再生铅合金 铅锑合金 ZSPbSb1 余量 1.5~3.5 0.10~0.25 - 0.01 0.03 0.02 0.01 - - 0.001 0.001 0.001 0.001 - ZSPbSb2 余量 3.6~7.5 0.26~0.50 - 0.02 0.05 0.03 0.02 - - 0.001 0.001 0.001 0.001 - 铅钙合金 ZSPbCa 余量 - 0.06~0.12 0.05~1.80 0.01~0.04 0.001 0.002 0.008 0.001 0.005 - 0.001 0.001 0.001 0.001 - 铅锡合金 ZSPbSn1 余量 - - 1.5~3.5 - - 0.03 0.03 0.03 0.1 - 0.002 0.02 - - - ZSPbSn2 余量 - - 3.6~7.5 - - 0.03 0.03 0.03 0.1 - 0.002 0.02 - - - 注:牌号表示方法:“ZS"为“再生”的汉语拼音首字母。 GB、T 2 二8 一—2。一7 5检验规则 5.1检查与验收 5.1.1再生铅及铅合金锭应由供方技术监督部门进行检验，保证产品质量符合本标准或订货单（或合 同）的规定，并填写质量证明书。 5.1.2需方应对收到的产品按本标准的规定进行检验，如检验结果与本标准或订货单（或合同）的规定 不符时，应在收到产品之日起15天内向供方提出，由供需双方协商解决。如需仲裁，仲裁取样在需方由 供需双方共同进行。 5.2组批 5.2.1再生铅及铅合金锭应成批提交检验，每批应由同一熔炼号的产品组成，批量不大于120 to 5.2.2根据需方需要，允许由同一牌号的多个生产批组成一个检验批，批量按需方要求执行。 5.3检验项目 每批再生铅及铅合金锭应进行化学成分和表面质量的检验。 5.4仲裁取样和制样 5.4.1仲裁取样数量：随机抽取再生铅及铅合金锭的2%作为样锭，样锭总数应为6的倍数，以便分组。 分组后不足6锭时，应从再生铅及铅合金锭中补足，但不得舍弃。 5.4.2仲裁取样方法:将抽取的样锭按每6个锭为一组。用钻孔或锯切法采取试样。钻孔或锯切时, 不得使用任何润滑剂，其速度不得使样品氧化。取样时应除去表皮，钻、锯深度不小于锭厚的三分之二。 具体如下： a） 钻孔法：用直径10 mm〜15 mm的钻头取样，将浇注面A与底面B依次排列成长方形，在长 方形上划2条对角线，与每锭纵向中心线相交的两点为该锭的取样点，如图1所示。 b） 锯切法：锯条于再生铅及铅合金锭垂直，通过钻孔法取样点横向锯切。 5.4.3试样的制备：将取得的试样制成不大于4 mm屑状，用磁体除净加工时带入的铁屑，仔细混匀后 以四分法缩至不小于360 g,作为仲裁分析样品。 图1再生铅及铅合金锭钻孔布点图 5.5检验结果判定 5.5.1杂质元素检验结果的修约及修约后数值的表示和判定，按GB/T 8170中的规定进行。 5.5.2再生铅及铅合金锭化学成分仲裁分析结果与本标准或订货单（或合同）的规定不符时，按批判不 合格。 5.5.3再生铅及铅合金锭的物理规格和表面质量不符合本标准或订货单（或合同）的规定，按锭判不 合格。 6标志、包装、贮存、运输和质量证明书 6.1标志 6.1.1每块再生铅及铅合金锭上应浇铸或打印上牌号、批号和商标。 6.1.2每捆再生铅及铅合金锭都应有醒目的不易脱落的标识，注明生产厂名称、产品名称、牌号、批号 和净量。 6.2包装 6.2.1每捆产品应用相应强度且不易锈蚀的包装带捆扎包装。 6.2.2需方对产品包装有特殊要求时，可由供需双方商定。 6.3运输与贮存 6.3.1再生铅及铅合金锭应用无腐蚀性物质的运输工具装运，防止被雨淋。 6.3.2再生铅及铅合金锭应贮存在通风、干燥、无腐蚀性物质的库房内。 6.3.3再生铅及铅合金锭在运输与贮存过程中，表面生成的白色、灰白色或黄白色薄膜，系由铅的自然 氧化性质决定的，不作报废依据。 6.4质量证明书 每批再生铅及铅合金锭都应附有质量证明书，其上注明： a） 供方名称和商标、地址、电话或传真； b） 产品名称和牌号； c） 批号； d） 净重和件数； e） 分析检验结果和技术监督部门印记； f） 本标准编号； g） 出厂日期。 7订货单（或合同）内容 本标准所列产品的订货单（或合同）内应包括下列内容： a） 产品名称； b） 牌号； c） 化学成分、物理规格、表面质量等特殊要求； d） 数量； e） 本标准编号; f） 其他。