标准编号:	DB11/ 3005-2017
中文名称:	建筑类涂料与胶粘剂挥发性有机化合物含量限值标准
英文名称:	Limit standards of volatile origanic compounds of architectural coatings and adhesives
行业分类:	DB    地方标准
发布机构:	北京市质量技术监督局
发布日期:	2017-04-12
实施日期:	2017-9-1
标准状态:	valid
被新标准替代:	DB11/ 1983-2022 建筑类涂料与胶粘剂挥发性有机化合物含量限值标准
翻译语言:	英文
文件格式:	PDF

Codeofchina.com is in charge of this English translation. In case of any doubt about the English translation, the Chinese original shall be considered authoritative. In order to boost the implementation of coordinated development of the Beijing-Tianjin-Hebei Region, Beijing Municipal Environmental Protection Bureau, Tianjin Environmental Protection Bureau, Hebei Provincial Environmental Protection Bureau, Administration of Quality and Technology Supervision, Tianjin Market and Quality Supervision Administration, and Hebei Provincial Administration of Quality and Technical Supervision have jointly organized and formulated this provincial standard, which is applicable to the Beijing-Tianjin-Hebei Region and issued hereby. The full text of this standard is mandatory. This standard is developed in accordance with the rules given in GB/T 1.1-2009. This standard was proposed by and is under the jurisdiction of Beijing Municipal Environmental Protection Bureau. This standard is jointly organized and implemented by Beijing Municipal Environmental Protection Bureau, Beijing Administration for Industry and Commerce, Beijing Municipal Administration of Quality and Technology Supervision, and Beijing Municipal Commission of Housing and Urban-Rural Development. Introduction This standard is formulated with a view to implementing Regulations of Beijing Municipality on Prevention and Control of Air Pollution so as to reduce the emission of volatile organic compounds during the application of architectural coatings and adhesives and improve regional atmospheric environment quality. Limit Standards of Volatile Organic Compounds of Architectural Coatings and Adhesives 1 Scope This standard specifies contents such as limit requirements, inspection method, inspection rules, and package marking of volatile organic compounds of architectural coatings and adhesives. This standard is applicable to all types of architectural coatings and adhesives produced, sold and applied in Beijing-Tianjin-Hebei region. 2 Normative References The following documents are indispensable for the application of this standard. For dated reference, only the edition cited applies. For undated references, the latest edition (including all amendments) of the referenced documents applies. GB/T 3186-2006 Paints, Varnishes and Raw Materials for Paints and Varnishes - Sampling GB/T 6750-2007 Paints and Varnishes - Determination of Density - Pyknometer Method (ISO 2811-1:1997, Paints and Varnishes - Determination of Density - Part 1: Pyknometer Method, IDT) GB/T 9754-2007 Paints and Varnishes - Determination of Specular Gloss of Non-metallic Paint Films at 20°, 60°and 85° (ISO 2813:1994, IDT) GB 24408-2009 Limit of Harmful Substances of Exterior Wall Coatings GB 18582-2008 Indoor Decorating and Refurbishing Materials - Limit of Harmful Substances of Interior Architectural Coatings GB/T 22374-2008 Floor Coatings GB/T 23986-2009 Paints and Varnishes - Determination of Volatile Organic Compound (VOC) Content - Gas-chromatographic Method GB/T 8170-2008 Rules of Rounding off for Numerical Values & Expression and Judgement of Limiting Values GB 30981-2014 Limit of Harmful Substances of Anticorrosion Coatings for Construction Steel Structure GB 18583-2008 Indoor Decorating and Refurbishing Materials - Limit of Harmful Substances of Adhesives JC 1066-2008 Limit of Harmful Substances of Building Waterproof Coatings 3 Terms and Definitions For the purposes of this document, the following terms and definitions apply. 3.1 volatile organic compounds (VOC) any organic compounds of which the initial boiling point is lower than or equal to 250℃ under standard atmosphere pressure of 101.3kPa 3.2 volatile organic compounds content (VOC content) content of volatile organic compounds obtained by testing the products with specified method Note 1: as for the exterior wall coatings, interior wall coatings, volatile-curing waterproof coatings, water-based floor coatings, water-based architectural anticorrosive coatings, and water-based adhesives, the volatile organic compounds content is that after moisture content is deducted from the product, expressed in gram per liter (g/L). Note 2: as for the reaction-curing waterproof coatings, solvent-based floor coatings, solvent-free floor coatings, solvent-based architectural anticorrosive coatings, and solvent-based adhesives, the volatile organic compounds content is that without deducting the moisture content from the product, expressed in gram per liter (g/L). Note 3: the volatile organic compounds content of the putty for exterior and interior walls is that without deducting the moisture content from the product, expressed in gram per kilogram (g/kg). 3.3 architectural coatings coatings used for architectural industry and relevant fields for protection and decoration, including exterior wall coatings, interior wall coatings, waterproof coatings, floor coatings, and architectural anticorrosive coatings in this standard 3.4 architectural adhesives adhesives, including solvent-based adhesives, water-based adhesive and body-type adhesives in this standard, which are used for architectural industry and relevant fields to bind the adherend together by pasting 3.5 heavy-duty coatings coatings that are applicable in harsh corrosive environment and have long-lasting service life 4 Limit Requirements The content of volatile organic compounds in the products shall be in accordance with those specified in Table 1. Table 1 Limit Requirements for Volatile Organic Compounds Content Product type Content limit Exterior wall coatings (g/L) Finish paints a Priming paints a Putty b ≤100 ≤80 ≤10 g/kg Interior wall coatings (g/L) Finish paints a Priming paints a Putty b Gloss (60°)≤10 Gloss (60°)>10 ≤50 ≤80 ≤50 ≤10 g/kg Waterproof coatings (g/L) Volatile-curing waterproof coatings a Reaction-curing waterproof coatings c Epoxy resin modified waterproof coatings Polyurea waterproof coatings Polyurethane waterproof coatings ≤10 ≤150 ≤50 ≤100 Floor coatings(g/L) Water-based a Solvent-based c, d Solvent-free ≤120 ≤420 ≤60 Architectural anticorrosive coatings(g/L) Water-based a Solvent-based c, e ≤150 ≤420 Solvent adhesives(g/L)c SBS adhesives ACR adhesives Other adhesives ≤600 ≤550 ≤650 Water-based adhesives (g/L)a Polyvinyl acetate adhesives Formal adhesives Rubber adhesives Polyurethanes adhesives VAE emulsion adhesives ACR adhesives Other adhesives ≤100 ≤150 ≤150 ≤100 ≤100 ≤100 ≤150 Body-type adhesives (g/kg) Silicone (including MS) adhesives Polyurethanes adhesives Polysulfide adhesives Epoxy adhesives ≤100 ≤50 ≤50 ≤50 a Dilution and mixture ratio is not considered for exterior wall coatings, interior wall coatings, volatile-curing waterproof coatings, water-based floor coatings, water-based architectural anticorrosive coatings and water-based adhesives. b Dilution and mixture ratio is not considered for paste putty used for exterior and interior walls. As for powdery putty, for the purpose of testing, the powder shall be mixed with other liquids such as water or adhesives according to the construction mixture ratio specified for the product. Where the construction mixture ratio is within a certain range, the testing shall be carried out after mixing with the minimum amount of water and the maximum amount of other liquids such as adhesives. c The reaction-curing waterproof coatings, solvent-based floor coatings, solvent-based architectural anticorrosive coatings and solvent-based adhesives shall be tested after being mixed according to the construction mixture ratio specified for the products. Where the diluent consumption is within certain range, determination shall be carried out after mixing the products according to the maximum dilution ratio specified by the construction mix ratio. d It is only applicable to solvent-based floor coatings produced in Tianjin and Hebei Province; solvent-based floor coatings produced in Beijing shall be subjected to the requirements of Action Plan of Cleaning Air of Beijing and related policies; floor coatings sold and used in Beijing-Tianjin-Hebei region shall be in accordance with the content limit for water-based and solvent-free coatings. e It only applicable to solvent-based architectural anticorrosive coatings produced, sold and used in Tianjin and Hebei Province, as well as solvent-based heavy-duty coatings used in municipal and traffic facilities in Beijing in cases where heavy anti-corrosion technology is necessary; the solvent-based architectural anticorrosive coatings produced in Beijing shall be subjected to the requirements of Action Plan of Cleaning Air of Beijing and related policies ; the architectural anticorrosive coatings which are sold and used (except for the above-mentioned heavy-duty anti-corrosion coating) shall be in accordance with the content limit for water-based anticorrosive coatings. 5 Inspection Method 5.1 Sampling The product shall be sampled in accordance with the requirements of GB/T 3186-2006. 5.2 Test method 5.2.1 The volatile organic compounds (VOC) in exterior wall coatings shall be tested in accordance with those specified in Annex A, GB 24408-2009, wherein the moisture content and density shall be tested in accordance with Annex B, GB 24408-2009 and GB/T 6750-2007 respectively. The test result of priming paint and finish paint shall be calculated in accordance with A.7.2 in Annex A, GB 24408-2009, and that of putty products shall be calculated in accordance with A.7.1 in Annex A, GB 24408-2009. Note: moisture content and density tests are not applicable to all the putty samples. 5.2.2 The volatile organic compounds (VOC) in interior wall coatings and volatile-curing waterproof coatings shall be tested in accordance with Annex A, GB 18582-2008, wherein the moisture content and density shall be tested in accordance with Annex B, GB 18582-2008 and GB/T 6750-2007 respectively. The test results of priming paints and finish paints shall be calculated in accordance with A.7.2 in Annex A, GB 18582-2008, and that of putty products shall be calculated in accordance with A.7.1 in Annex A, GB 18582-2008. Note: moisture content and density tests are not applicable to all the putty samples. 5.2.3 The film gloss of interior wall coatings shall be tested in accordance with GB/T 9754-2007 with the testing conditions of (105±2)℃ and a drying time of 2h. 5.2.4 The volatile organic compounds (VOC) in reaction-curing waterproof coatings shall be tested in accordance with Annex A, JC 1066-2008. 5.2.5 The volatile organic compounds (VOC) in floor coatings shall be tested in accordance with GB/T 22374-2008. 5.2.6 The volatile organic compounds (VOC) in water-based architectural anticorrosive coatings shall be tested in accordance with GB/T 23986-2009, wherein the moisture content and density shall be tested in accordance with Annex B, GB 18582-2008 and GB/T 6750-2007 respectively. The test results of coating products shall be calculated in accordance with 10.4, GB/T 23986-2009. 5.2.7 The volatile organic compounds (VOC) in solvent-based architectural anticorrosive coatings shall be tested in accordance with Annex A, GB 30981-2014.

Foreword i Introduction i 1 Scope 2 Normative References 3 Terms and Definitions 4 Limit Requirements 5 Inspection Method 6 Inspection Rules 7 Package Marking Annex A (Informative) Examples for Contents of Supplementary Package Marking for Architectural Coatings and Adhesives

ICS 13.040.40 Z60 北京市地方标准 DB 11/ 3005—2017 建筑类涂料与胶粘剂挥发性有机化合物 含量限值标准 Limit standards of volatile organic compounds of architectural coatings and adhesives 2017-04-12发布 2017-09-01实施 北京市质量技术监督局 发布 前 言 为推进京津冀协同发展战略实施，北京市环境保护局、天津市环境保护局、河北省环境保护厅、北京市质量技术监督局、天津市市场和质量监督管理委员会、河北省质量技术监督局共同组织制定本地方标准，在京津冀区域内适用，现予发布。 本标准为全文强制。 本标准依据GB/T 1.1-2009给出的规则起草。 本标准由北京市环境保护局提出并归口。 本标准起草单位： （北京组）北京市环境保护科学研究院、北京建筑材料检验研究院有限公司、北京建筑大学。 （天津组）天津市环境监测中心、北京市环境保护科学研究院。 （河北组）河北海航企业管理咨询有限公司、河北安亿环境科技有限公司、河北环学环保科技有限公司、河北省环境科学学会、北京市环境保护科学研究院、河北润峰环境检测服务有限公司、河北晨阳工贸集团有限公司、衡水新光化工有限责任公司、石家庄市油漆厂、河北省粘接与涂料协会、北京惠盟创洁环保科技有限公司。 本标准主要起草人： （北京组） 聂磊、高美平、袁勋、高喜超、檀春丽、闫磊、张澜夕、杜晓丽、申前进、邢可欣 （天津组） 邓小文、关玉春、吴宇峰、聂磊、崔连喜、张肇元、王效国、杨虹、王琳、刘琨 （河北组）李占广、马贵宝、于海、程娜、聂磊、耿耀宗、耿树行、于欣沛、胡中源、田海宁、凌芹、吴唐健、马瑞兰、贾小芳、刘芳萍、柳坤然 本标准由北京市环境保护局、北京市工商行政管理局、北京市质量技术监督局、北京市住房和城乡建设委员会共同组织实施。 引 言 为贯彻《北京市大气污染防治条例》，降低建筑类涂料与胶粘剂使用过程挥发性有机化合物的排放，改善区域大气环境质量，制定本标准。 建筑类涂料与胶粘剂挥发性有机化合物含量限值标准 1 范围 本标准规定了建筑类涂料与胶粘剂中挥发性有机化合物含量限值要求、检验方法、检验规则、包装标志等内容。 本标准适用于京津冀区域内生产、销售和使用的各类建筑类涂料与胶粘剂。 2 规范性引用文件 下列文件对于本标准的应用是必不可少的。凡是注日期的引用文件，仅所注日期的版本适用于本标准。凡是不注日期的引用文件，其最新版本（包括所有的修改单）适用于本文件。 GB/T 3186-2006 色漆、清漆和色漆与清漆用原材料取样 GB/T 6750-2007 色漆和清漆 密度的测定 比重瓶法(ISO 2811-1:1997, Panits and varnishes-Determination of density-Part 1:Pyknometer method, IDT) GB/T 9754-2007 色漆和清漆 不含金属颜料的色漆漆膜的20°、60°和85°镜面光泽的测定（ISO 2813:1994，IDT) GB 24408-2009 建筑用外墙涂料中有害物质限量 GB 18582-2008 室内装饰装修材料 内墙涂料中有害物质限量 GB/T 22374-2008 地坪涂装材料 GB/T 23986-2009 色漆和清漆 挥发性有机化合物（VOC）含量的测定 气相色谱法 GB/T 8170-2008 数值修约规则与极限数值的表示和判定 GB 30981-2014 建筑钢结构防腐涂料中有害物质限量 GB 18583-2008 室内装饰装修材料 胶粘剂中有害物质限量 JC 1066-2008 建筑防水涂料中有害物质限量 3 术语和定义 下列术语和定义适用于本文件。 3.1 挥发性有机化合物（VOC）volatile organic compounds 在101.3kPa标准大气压下，任何初沸点低于或等于250℃的有机化合物。 3.2 挥发性有机化合物含量（VOC含量）volatile organic compounds content 按规定的测试方法测试产品所得到的挥发性有机化合物的含量。 注1：外墙涂料、内墙涂料、挥发固化型防水涂料、水性地坪涂料、水性建筑防腐涂料、水基型胶粘剂为产品扣除水分后的挥发性有机化合物的含量，以克每升（g/L）表示。 注 2：反应固化型防水涂料、溶剂型地坪涂料、无溶剂型地坪涂料、溶剂型建筑防腐涂料、溶剂型胶粘剂为产品不扣除水分的挥发性有机化合物的含量，以克每升（g/L）表示。 注 3：外墙与内墙腻子为产品不扣除水分的挥发性有机化合物含量，以克每千克（g/kg）表示。 3.3 建筑类涂料 architectural coatings 用于建筑行业及相关领域，起保护、装饰作用的涂料。本标准包括外墙涂料、内墙涂料、防水涂料、地坪涂料与建筑防腐涂料。 3.4 建筑类胶粘剂 architectural adhesives 用于建筑行业及相关领域，通过粘和作用，使被粘物结合在一起的胶粘剂。本标准包括溶剂型胶粘剂、水基型胶粘剂与本体型胶粘剂。 3.5 重防腐涂料 heavy-duty coatings 能在严酷的腐蚀环境下应用，并具有长效使用寿命的涂料。 4 限值要求 产品中挥发性有机化合物含量应符合表 1 的要求。 表1 挥发性有机化合物含量限值要求 产品类型 含量限值 外墙涂料（g/L） 面漆a 底漆a 腻子b ≤100 ≤80 ≤10 g/kg 内墙涂料（g/L） 面漆a 底漆a 腻子b 光泽（60°）≤10 光泽（60°）＞10 ≤50 ≤80 ≤50 ≤10 g/kg 防水涂料（g/L） 挥发固化型防水涂料a 反应固化型防水涂料c 环氧树脂改性防水涂料 聚脲防水涂料 聚氨酯防水涂料 ≤10 ≤150 ≤50 ≤100 地坪涂料（g/L） 水性a 溶剂型c，d 无溶剂型 ≤120 ≤420 ≤60 建筑防腐涂料（g/L） 水性a 溶剂型c，e ≤150 ≤420 溶剂型胶粘剂（g/L）c SBS胶粘剂 丙烯酸酯类胶粘剂 其他胶粘剂 ≤600 ≤550 ≤650 表 1 （续） 水基型胶粘剂（g/L）a 聚乙酸乙烯酯类胶粘剂 缩甲醛类胶粘剂 橡胶类胶粘剂 聚氨酯类胶粘剂 VAE乳液类胶粘剂 丙烯酸酯类胶粘剂 其他类胶粘剂 ≤100 ≤150 ≤150 ≤100 ≤100 ≤100 ≤150 本体型胶粘剂（g/kg） 有机硅类（含MS） 胶粘剂 聚氨酯类胶粘剂 聚硫类胶粘剂 环氧类胶粘剂 ≤100 ≤50 ≤50 ≤50 a 外墙涂料、内墙涂料、挥发固化型防水涂料、水性地坪涂料、水性建筑防腐涂料、水基型胶粘剂不考虑稀释配比。 b 外墙与内墙腻子中膏状腻子不考虑稀释配比。粉状腻子按照产品规定的施工配比将粉体与水或胶粘剂等其他液体混合后测试。如施工配比在某一范围时，应按照水用量最小、胶粘剂等其他液体用量最大的施工配比混合后测试。 c 反应固化型防水涂料、溶剂型地坪涂料、溶剂型建筑防腐涂料、溶剂型胶粘剂按照产品规定的施工配比混合后测试。如稀释剂的使用量为某一范围时，应按照产品施工配比规定的最大稀释比例混合后进行测试。 d 仅适用于在天津市和河北省生产的溶剂型地坪涂料；北京市生产的溶剂型地坪涂料应按照北京市清洁空气行动计划及相关政策执行；京津冀区域销售和使用的地坪涂料应符合水性和无溶剂型的含量限值。 e 仅适用于在天津市和河北省生产、销售、使用的溶剂型建筑防腐涂料，以及北京市在市政、交通设施等必须采用重防腐工艺时所使用的溶剂型重防腐涂料；北京市生产的溶剂型建筑防腐涂料应按照北京市清洁空气行动计划及相关政策执行，销售和使用的建筑防腐涂料（除前述重防腐情况外）应执行水性防腐涂料的含量限值。 5 检验方法 5.1 取样 产品取样按照 GB/T 3186-2006 的规定进行。 5.2 试验方法 5.2.1 外墙涂料中挥发性有机化合物（VOC）的检测按照GB 24408-2009附录A的规定进行，其中水分含量的检测按照GB 24408-2009附录B进行，密度的检测按照GB/T 6750-2007进行。底漆和面漆产品测试结果的计算按照GB 24408-2009附录A中A.7.2进行，腻子产品测试结果的计算按照GB 24408-2009附录A中A.7.1进行。 注：所有腻子样品不做水分含量和密度的测试。 5.2.2 内墙涂料与挥发固化型防水涂料中挥发性有机化合物（VOC）的检测按照GB 18582-2008附录A的规定进行，其中水分含量的检测按照GB 18582-2008附录B进行，密度的检测按照GB/T 6750-2007进行。底漆和面漆产品测试结果的计算按照GB 18582-2008附录A中A.7.2进行，腻子产品测试结果的计算按照GB 18582-2008附录A中A.7.1进行。 注：所有腻子样品不做水分含量和密度的测试。 5.2.3 内墙涂料涂膜光泽的检测按照GB/T 9754-2007进行，测试条件为（105±2）℃，烘干2小时。 5.2.4 反应固化型防水涂料中挥发性有机化合物（VOC）的检测按照JC 1066-2008附录A的规定进行。 5.2.5 地坪涂料中挥发性有机化合物（VOC）的检测按照GB/T 22374-2008的规定进行。 5.2.6 水性建筑防腐涂料中挥发性有机化合物（VOC）的检测按照GB/T 23986-2009的规定进行，其中水分含量的检测按照GB 18582-2008附录B进行，密度的检测按照GB/T 6750-2007进行。涂料产品测试结果的计算按照GB/T 23986-2009中10.4进行。 5.2.7 溶剂型建筑防腐涂料中挥发性有机化合物（VOC）的检测按照GB 30981-2014附录A的规定进行。 5.2.8 胶粘剂中挥发性有机化合物（VOC）的检测按照GB 18583-2008附录F的规定进行。 6 检验规则 6.1 检验项目 6.1.1 本标准所列的全部要求均为型式检验项目。 6.1.2 在正常生产情况下，每年至少进行一次型式检验。 6.1.3 有下列情况之一时应随时进行型式检验： ——新产品最初定型时； ——生产配方、工艺、关键原材料来源及产品施工配比有较大改变时； ——停产三个月后又恢复生产时。 6.1.4 销售单位在京津冀区域内销售本标准规定的产品，销售单位应能提供有效的型式检验报告。 6.2 检验结果 6.2.1 检验结果的判定按照GB/T 8170-2008 中修约值比较法进行。 6.2.2 粉状腻子、反应固化型防水涂料、溶剂型地坪涂料、溶剂型建筑防腐涂料、溶剂型胶粘剂产品报出检验结果时应同时注明产品明示的施工配比。 6.2.3 检验结果达到本标准表1的要求时，产品为符合本标准要求。 7 包装标志 7.1 2017年9月1日起，在京津冀区域内生产、销售本标准规定的产品，除原有产品说明外，需要在包装标志上补充标明以下内容(示例参照附录A)： a) 本标准规定的产品类型和用途。 b) 产品所含挥发性有机化合物含量，可以选用以下两种形式之一表述： 1) 挥发性有机化合物含量值； 2) 挥发性有机化合物含量不超过表1规定的限值。 c) 对于施工时需要稀释的产品，则须显示推荐的稀释溶剂和稀释量（对于用水稀释的胶粘剂或建筑类涂料无需说明）。对于由双组分或多组分配套组成的产品，则须显示各组分的施工配比。 附 录 A （资料性附录） 建筑类涂料与胶粘剂补充包装标志内容示例 A.1 在京津冀区域生产、销售建筑类涂料与胶粘剂，需补充的包装标志内容示例见表A.1 表A.1 建筑类涂料与胶粘剂需补充包装标志内容示例 产品类型 外墙涂料 产品大类 底漆 产品小类 / 产品用途 适用于别墅、酒店、学校、医院、写字楼和家居外墙的装饰和保护。 挥发性有机化合物含量 挥发性有机化合物含量 X g/L 或 挥发性有机化合物含量 ≤ X g/L 推荐稀释剂 / 稀释比例 / 施工配比 / 产品类型 建筑防腐涂料 产品大类 溶剂型建筑防腐涂料 产品小类 / 产品用途 适用于家装、公共环境、建筑混凝土和钢结构表面防护与装饰。 挥发性有机化合物含量 挥发性有机化合物含量 X g/L 或 挥发性有机化合物含量 ≤ X g/L 推荐稀释剂 聚氨酯涂料稀释剂 稀释比例 稀释剂/涂料 ≤ X 施工配比 / 产品类型 胶粘剂 产品大类 溶剂型胶粘剂 产品小类 聚氨酯胶粘剂 产品用途 适用于室内外装饰装修和建筑施工工程的粘结密封。 挥发性有机化合物含量 挥发性有机化合物含量 X g/L 或 挥发性有机化合物含量 ≤ X g/L 推荐稀释剂 / 稀释比例 / 施工配比 组分A：组分B = 1：X