标准编号:	DB37/ 2375-2019
中文名称:	工业炉窑大气污染物排放标准
英文名称:	Emission standard of air pollutants for industrial kiln and furnace
行业分类:	DB    地方标准
发布机构:	山东省市场监督管理局 山东省生态环境厅
发布日期:	2019-06-03
实施日期:	2019-11-1
标准状态:	valid
替代旧标准:	DB37/ 2375-2013 山东省工业炉窑大气污染物排放标准
翻译语言:	英文
文件格式:	PDF
中文字符数:	7000 字
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Codeofchina.com is in charge of this English translation. In case of any doubt about the English translation, the Chinese original shall be considered authoritative. This standard is developed in accordance with the rules given in GB/T 1.1-2009. This standard replaces DB 37/ 2375-2013 Emission standard of air pollutants for industrial furnace and kiln in Shandong Province, and the following main technical changes have been made with respect to DB 37/ 2375-2013: ——the pollutant control factors are adjusted; ——the emission limits for some pollutants are tightened; ——the emission limit for chromium and its compounds is added; ——the benchmark oxygen content of some industrial furnaces and kilns is adjusted; ——the criteria for compliance are defined. During the transition period before the implementation of this standard, the characteristic air pollutants emitted by existing industrial furnaces and kilns shall comply with the relevant requirements of DB 37/ 2375-2013 Emission standard of air pollutants for industrial furnace and kiln in Shandong Province; the particulate matters, sulfur dioxide and nitrogen oxides emitted by the industrial furnaces and kilns shall comply with the relevant requirements of DB37/ 2376. This standard was proposed by the Department of Ecology and Environment of Shandong Province. This standard is under the jurisdiction of the Technical Committee for Standardization of Environmental Protection of Shandong Province. This standard was firstly issued in 2013 and is revised for the first time. Emission standard of air pollutants for industrial furnace and kiln 1 Scope This standard specifies the emission limits, monitoring and control requirements for characteristic air pollutants from industrial furnaces and kilns in Shandong Province, and the implementation and supervision of the standard. This standard is applicable to the emission control of characteristic air pollutants from existing industrial furnaces and kilns in Shandong Province, and to the environmental impact assessment, environmental protection facility design and acceptance and pollutant discharge permit for the construction projects of industrial furnaces and kilns, as well as the emission control of air pollutants after such industrial furnaces and kilns are put into operation. This standard is not applicable to furnaces and kilns in iron and steel industry, building materials industry, hazardous waste incineration and other industries in Shandong Province, and their emissions of air pollutants shall comply with the national or corresponding professional standards for emission of air pollutants in Shandong Province. 2 Normative references The following referenced documents are indispensable for the application of this standard. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. GB/T 16157 Determination of particulates and sampling methods of gaseous pollutants emitted from exhaust gas of stationary source HJ/T 27 Stationary source emission—Determination of hydrogen chloride—Mercuric thiocyanate spectrophotometric method HJ/T 40 Stationary source emission—Determination of benzo(a)pyrene—High performance liquid chromatography HJ/T 45 Stationary source emission—Determination of asphaltic smoke—Gravimetric method HJ/T 64.1 Stationary source emission—Determination of cadmium—Flame atomic absorption spectrophotometric method HJ/T 64.2 Stationary source emission—Determination of cadmium—Graphitic furnace atomic absorption spectrophotometric method HJ/T 64.3 Stationary source emission—Determination of cadmium—p-Azobenzenediazoaminazobenzene sulfonic acid spectrophotometric method HJ/T 67 Stationary source emission—Determination of fluoride—Ion selective electrode method HJ 75 Specifications for continuous emissions monitoring of SO2, NOX, and particulate matter in the flue gas emitted from stationary sources HJ 76 Specifications and test procedures for continuous emission monitoring system for SO2, NOx and particulate matter in flue gas emitted from stationary sources HJ 77.2 Ambient air and flue gas—Determination of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs)—Isotope dilution HRGC-HRMS HJ/T 373 Technical specifications of quality assurance and quality control for monitoring of stationary pollution source (on trial) HJ/T 397 Technical specifications for emission monitoring of stationary source HJ/T 398 Stationary source emission—Determination of blackness of smoke plumes—Ringelmann smoke chart HJ 540 Stationary source emission—Determination of arsenic—Silver diethyldithiocarbamate spectrophotometric method HJ 543 Stationary source emission—Determination of mercury—Cold atomic absorption spectrophotometry (Provisional) HJ 548 Stationary source emissions—Determination of hydrogen chloride—Silver nitrate titration HJ 549 Ambient air and stationary source emissions—Determination of hydrogen chloride—Ion chromatography HJ 646 Ambient air and stationary source emissions—Determination of gas and particle-phase polycyclic aromatic hydrocarbons with gas chromatography/mass spectrometry HJ 647 Ambient air and stationary source emissions—Determination of gas and particle-phase polycyclic aromatic hydrocarbons—High performance liquid chromatography HJ 657 Ambient air and stationary source emission—Determination of metals in ambient particulate matter—Inductively coupled plasma/mass spectrometry (ICP-MS) HJ 684 Stationary source emission—Determination of beryllium—Graphite furnace atomic absorption spectrophotometric method HJ 685 Stationary source emission—Determination of lead—Flame atomic absorption spectrometric method HJ 688 Stationary source emission—Determination of hydrogen fluoride—Ion chromatography (Provisional) HJ 777 Ambient air and waste gas from stationary sources emission—Determination of metal elements in ambient particle matter—Inductively coupled plasma optical emission spectrometry HJ 819 Self-monitoring technology guidelines for pollution sources—General rule HJ 836 Stationary source emission—Determination of mass concentration of particulate matter at low concentration—Manual gravimetric method 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1 industrial furnace and kiln thermal equipment for smelting, roasting, sintering, melting and heating materials or workpieces with heat generated by fuel combustion or electric energy conversion in industrial production 3.2 existing industrial furnace and kiln industrial furnaces and kilns that have been completed and put into operation or whose environmental impact assessment documents have been reviewed, approved or put on records before the implementation date of this standard 3.3 new industrial furnace and kiln newly built, rebuilt and expanded industrial furnaces and kilns whose environmental impact assessment documents have been reviewed, approved or put on records from the implementation date of this standard 3.4 dry tail gas for furnace and kiln waste gas produced in the drying process of materials by mixing a certain amount of fresh air with the hot flue gas produced by the furnace and kiln 3.5 standard condition condition of flue gas at the temperature of 273.15 K and the pressure of 101 325 Pa; all the emission concentrations specified in this standard are values in dry flue gas under standard condition 3.6 benchmark exhaust volume per unit product upper limit of exhaust volume per unit product specified for verifying the emission concentration of air pollutants 3.7 oxygen content excess free oxygen contained in flue gas during fuel combustion, which is usually expressed as dry basis volume percentage 4 Technical contents 4.1 Pollutants emission control requirements 4.1.1 The emission concentration limits in Table 1 shall be implemented for new and existing industrial furnaces and kilns from the date of implementation of this standard. 4.1.2 The pollutants to be monitored specifically for different industrial furnaces and kilns shall be determined according to the pollutant emission permit and national industry standards. The emission concentration limits of pollutants not included in this standard shall comply with the relevant national and Shandong provincial standards. Table 1 Emission concentration limits of characteristic air pollutants from industrial furnaces and kilns Pollutant Unit Emission limit Blackness of flue gas Ringelmann blackness (level) 1.0 Fluoride (in F) mg/m3 3.0 (for metal smelting furnace); 6.0 (for other furnaces and kilns) Lead and its compounds mg/m3 0.5 (for metal smelting furnace); 0.1 (for other furnaces and kilns) Mercury and its compounds mg/m3 0.01 Beryllium and its compounds mg/m3 0.01 Arsenic and its compounds mg/m3 0.4 Cadmium and its compounds mg/m3 0.05 (for tin, antimony and mercury industries, reclaimed copper, aluminum, lead and zinc industries); 0.8 (for other furnaces and kilns) Chromium and its compounds mg/m3 1.0 Hydrogen chloride mg/m3 30 Benzo(a)pyrene µg/m3 0.3 Dioxins ng-TEQ/m3 0.4 Asphaltic smoke mg/m3 5.0 4.1.3 If the competent department of ecology and environment under the State Council or Shandong Provincial People's Government clearly stipulates the territorial scope and time for implementing the special emission limits of air pollutants, in addition to this standard, the industrial furnaces and kilns within the territorial scope shall also comply with the special emission limits in the national standards as required. 4.2 Emission pipe height requirements The emission pipe height shall in no way be less than 15 m, and the specific height shall be determined according to the requirements of environmental impact assessment documents that have been reviewed, approved or put on records. 5 Requirements for pollutant monitoring 5.1 Requirements for sampling and monitoring of pollutants 5.1.1 The enterprises shall, in accordance with the requirements of relevant laws and regulations, establish an enterprise monitoring system, formulate a monitoring scheme, carry out self-monitoring over the pollutant emissions and the impact on the surrounding environment quality, keep the original monitoring records, and publish the monitoring results. The formulation of enterprises' self-monitoring schemes, monitoring quality assurance and quality control shall comply with the requirements of HJ/T 373, HJ 819 and HJ 836. 5.1.2 The requirements for installing automatic monitoring equipment for pollutant emissions in industrial furnaces and kilns shall be in accordance with HJ 75 and HJ 76, as well as relevant laws and regulations. 5.1.3 The emission pipes shall be provided with sampling holes and permanent monitoring platforms, whose arrangement shall be carried out according to relevant requirements of GB/T 16157, HJ/T 397, HJ 75, HJ 76 and HJ 836, and standardized permanent signs for emission outlets shall be set up. 5.1.4 Sampling frequency and method of pollution sources during supervisory monitoring shall meet the requirements of GB/T 16157, HJ/T 397, HJ 836 and other relevant standards. 5.1.5 The method standards listed in Table 2 shall be adopted for the determination of the emission concentration of air pollutants. After the promulgation and implementation of this standard, any newly issued national standards in regard to environmental monitoring and analysis methods, if their application scopes are the same, are also applicable to the determination of pollutants corresponding to this standard.

Foreword i 1 Scope 2 Normative references 3 Terms and definitions 4 Technical contents 5 Requirements for pollutant monitoring 6 Criteria for compliance 7 Implementation and supervision

ICS 13.040.40 Z 60 DB37 山东省地方标准 DB 37/ 2375—2019 代替 DB37/ 2375—2013 工业炉窑大气污染物排放标准 Emission standard of air pollutants for industrial furnace and kiln 2019 - 06 - 03发布 2019 - 11 - 01实施 发布 目 次 前言 II 1 范围 1 2 规范性引用文件 1 3 术语和定义 2 4 技术内容 2 5 污染物监测要求 3 6 达标判定 5 7 实施与监督 5 前 言 本标准按照GB/T 1.1—2009给出的规则起草。 本标准代替《山东省工业炉窑大气污染物排放标准》(DB37/ 2375—2013)，与DB37/ 2375—2013相比主要技术变化如下： ——调整了污染物控制因子； ——加严了部分污染物的排放限值； ——增加了铬及其化合物排放限值； ——调整部分工业炉窑基准氧含量； ——明确了达标判定方法。 现有工业炉窑在执行本标准前的过渡期内，其排放的特征大气污染物按照《山东省工业炉窑大气污染物排放标准》(DB37/ 2375—2013)有关要求执行；工业炉窑排放的颗粒物、二氧化硫、氮氧化物按照DB37/ 2376的有关要求执行。 本标准由山东省生态环境厅提出。 本标准由山东省环保标准化技术委员会归口。 本标准起草单位：山东省生态环境规划研究院、山东师范大学。 本标准主要起草人：李玄、史会剑、苏志慧、刘厚凤、周艳明、李昕婧、魏敏。 本标准首次发布于2013年，本次为第一次修订。 工业炉窑大气污染物排放标准 1　范围 本标准规定了山东省工业炉窑特征大气污染物的排放限值、监测和监控要求，以及标准的实施与监督等相关规定。 本标准适用于山东省现有工业炉窑的特征大气污染物排放管理，以及工业炉窑建设项目的环境影响评价、环境保护设施设计、环境保护设施验收、排污许可及其投产后的大气污染物排放管理。 本标准不适用于山东省钢铁工业、建材工业、危险废物焚烧等行业的炉窑装置，其排放大气污染物执行国家或山东省相应的行业大气污染物排放标准。 2　规范性引用文件 下列文件对于本文件的应用是必不可少的。凡是注日期的引用文件，仅所注日期的版本适用于本文件。凡是不注日期的引用文件，其最新版本（包括所有的修改单）适用于本文件。 GB/T 16157　固定污染源排气中颗粒物测定与气态污染物采样方法 HJ/T 27　固定污染源排气中氯化氢的测定　硫氰酸汞分光光度法 HJ/T 40　固定污染源排气中苯并(a)芘的测定　高效液相色谱法 HJ/T 45　固定污染源排气中沥青烟的测定　重量法 HJ/T 64.1　大气固定污染源　镉的测定　火焰原子吸收分光光度法 HJ/T 64.2　大气固定污染源　镉的测定　石墨炉原子吸收分光光度法 HJ/T 64.3　大气固定污染源　镉的测定　对-偶氮苯重氮氨基偶氮苯磺酸分光光度法 HJ/T 67　大气固定污染源　氟化物的测定　离子选择电极法 HJ 75　固定污染源烟气（SO2、NOX、颗粒物）排放连续监测技术规范 HJ 76　固定污染源烟气（SO2、NOX、颗粒物）排放连续监测系统技术要求及检测方法 HJ 77.2　环境空气和废气　二噁英类的测定　同位素稀释高分辨气相色谱—高分辨质谱法 HJ/T 373　固定污染源监测质量保证与质量控制技术规范（试行） HJ/T 397　固定源废气监测技术规范 HJ/T 398　固定污染源排放　烟气黑度的测定　林格曼烟气黑度图法 HJ 540　固定污染源废气　砷的测定　二乙基二硫代氨基甲酸银分光光度法 HJ 543　固定污染源废气　汞的测定　冷原子吸收分光光度法（暂行） HJ 548　固定污染源废气　氯化氢的测定　硝酸银容量法 HJ 549　环境空气和废气　氯化氢的测定　离子色谱法 HJ 646　环境空气和废气　气相和颗粒物中多环芳烃的测定　气相色谱—质谱法 HJ 647　环境空气和废气　气相和颗粒物中多环芳烃的测定　高效液相色谱法 HJ 657　空气和废气　颗粒物中铅等金属元素的测定　电感耦合等离子体质谱法 HJ 684　固定污染源废气　铍的测定　石墨炉原子吸收分光光度法 HJ 685　固定污染源废气　铅的测定　火焰原子吸收分光光度法 HJ 688　固定污染源废气　氟化氢的测定　离子色谱法（暂行） HJ 777　空气和废气　颗粒物中金属元素的测定　电感耦合等离子体发射光谱法 HJ 819　排污单位自行监测技术指南　总则 HJ 836　固定污染源废气　低浓度颗粒物的测定　重量法 3　术语和定义 下列术语和定义适用于本文件。 3.1　 工业炉窑　industrial furnace and kiln 在工业生产中用燃料燃烧或电能转换产生的热量，将物料或工件进行冶炼、焙烧、烧结、熔化、加热等工序的热工设备。 3.2　 现有工业炉窑　existing industrial furnace and kiln 本标准实施之日前已建成投产或环境影响评价文件已通过审批、审核或备案的工业炉窑。 3.3　 新建工业炉窑　new industrial furnace and kiln 本标准实施之日起环境影响评价文件通过审批、审核或备案的新建、改建、扩建工业炉窑。 3.4　 炉窑干燥尾气　dry tail gas for furnace and kiln 利用炉窑产生的热烟气，掺混一定量的新鲜空气，对物料进行干燥过程中产生的废气。 3.5　 标准状态　standard condition 烟气在温度为273.15 K，压力为101 325 Pa时的状态，简称“标态”。本标准规定的排放浓度均指标准状态下的干烟气中的数值。 3.6　 单位产品基准排气量　benchmark exhaust volume per unit product 用于核定大气污染物排放浓度而规定的生产单位产品的排气量上限值。 3.7　 氧含量　oxygen content 燃料燃烧时，烟气中含有的多余的自由氧，通常以干基容积百分数来表示。 4　技术内容 4.1　污染物排放控制要求 4.1.1　新建和现有工业炉窑自本标准实施之日起，执行表1的排放浓度限值。 4.1.2　不同工业炉窑具体监控的污染物按照排污许可证和国家行业标准确定，本标准未包含污染物的排放浓度限值执行国家和山东省有关排放标准。 表1　工业炉窑特征大气污染物排放浓度限值 污染物项目 单位 排放限值 烟气黑度 林格曼黑度(级) 1.0 氟化物（以F计） mg/m3 3.0(金属熔炼炉)； 6.0(其他炉窑) 铅及其化合物 mg/m3 0.5(金属熔炼炉)； 0.1(其他炉窑) 汞及其化合物 mg/m3 0.01 铍及其化合物 mg/m3 0.01 砷及其化合物 mg/m3 0.4 镉及其化合物 mg/m3 0.05（锡、锑、汞工业，再生铜、铝、铅、锌工业）； 0.8（其他炉窑） 铬及其化合物 mg/m3 1.0 氯化氢 mg/m3 30 苯并(a)芘 µg/m3 0.3 二噁英 ng-TEQ/m3 0.4 沥青烟 mg/m3 5.0 4.1.3　国务院生态环境主管部门或山东省人民政府明确规定执行大气污染物特别排放限值的地域范围和时间的，该地域范围内的工业炉窑除应执行本标准外，还应按规定达到国家标准中特别排放限值。 4.2　排气筒高度要求 所有排气筒的高度应不低于15 m，具体高度按通过审批、审核或备案的环境影响评价文件要求确定。 5　污染物监测要求 5.1　污染物采样与监测要求 5.1.1　企业应按照有关法律法规要求，建立企业监测制度，制定监测方案，对污染物排放状况及其周边环境质量的影响开展自行监测，保存原始监测记录，并公布监测结果。企业自行监测方案制定、监测质量保证和质量控制等应符合 HJ/T 373、HJ 819和HJ 836的要求。 5.1.2　工业炉窑安装污染物排放自动监控设备的要求，按HJ 75、HJ 76等相关要求及有关法律和规定执行。 5.1.3　排气筒应设置采样孔和永久监测平台，采样孔和平台建设按GB/T 16157、HJ/T 397、HJ 75、HJ 76和HJ 836等相关要求执行，同时设置规范的永久性排污口标志。 5.1.4　实施监督性监测期间的采样频次和污染源采样方法应符合GB/T 16157、HJ/T 397、HJ 836等相关标准的要求。 5.1.5　对大气污染物排放浓度的测定采用表2所列的方法标准。本标准发布实施后，有新发布的国家环境监测分析方法标准，其方法适用范围相同的，也适用于本排放标准对应污染物的测定。 表2　大气污染物浓度测定方法标准 序号 污染物项目 方法标准名称 方法标准编号 1 烟气黑度 固定污染源排放　烟气黑度的测定　林格曼烟气黑度图法 HJ/T 398 2 氟化物 大气固定污染源　氟化物的测定　离子选择电极法 HJ/T 67 固定污染源废气　氟化氢的测定　离子色谱法（暂行） HJ 688 3 铅及其化合物 固定污染源废气　铅的测定　火焰原子吸收分光光度法 HJ 685 空气和废气颗粒物中铅等金属元素的测定　电感耦合等离子体质谱法 HJ 657 空气和废气颗粒物中金属元素的测定　电感耦合等离子体发射光谱法 HJ 777 4 汞及其化合物 固定污染源废气　汞的测定　冷原子吸收分光光度法（暂行） HJ 543 5 铍及其化合物 固定污染源废气　铍的测定　石墨炉原子吸收分光光度法 HJ 684 空气和废气颗粒物中铅等金属元素的测定　电感耦合等离子体质谱法 HJ 657 空气和废气颗粒物中金属元素的测定　电感耦合等离子体发射光谱法 HJ 777 6 砷及其化合物 固定污染源废气　砷的测定　二乙基二硫代氨基甲酸银分光光度法 HJ 540 空气和废气颗粒物中铅等金属元素的测定　电感耦合等离子体质谱法 HJ 657 空气和废气颗粒物中金属元素的测定　电感耦合等离子体发射光谱法 HJ 777 7 镉及其化合物 大气固定污染源　镉的测定　火焰原子吸收分光光度法 HJ/T 64.1 大气固定污染源　镉的测定　石墨炉原子吸收分光光度法 HJ/T 64.2 大气固定污染源　镉的测定　对-偶氮苯重氮氨基偶氮苯磺酸分光光度法 HJ/T 64.3 空气和废气颗粒物中铅等金属元素的测定　电感耦合等离子体质谱法 HJ 657 空气和废气颗粒物中金属元素的测定　电感耦合等离子体发射光谱法 HJ 777 8 铬及其化合物 空气和废气颗粒物中铅等金属元素的测定　电感耦合等离子体质谱法 HJ 657 空气和废气颗粒物中金属元素的测定　电感耦合等离子体发射光谱法 HJ 777 9 氯化氢 固定污染源排气中氯化氢的测定　硫氰酸汞分光光度法 HJ/T 27 固定污染源废气　氯化氢的测定　硝酸银容量法 HJ 548 环境空气和废气　氯化氢的测定　离子色谱法 HJ 549 10 苯并(a)芘 固定污染源排气中苯并(a)芘的测定 高效液相色谱法 HJ/T 40 环境空气和废气　气相和颗粒物中多环芳烃的测定　气相色谱-质谱法 HJ 646 环境空气和废气　气相和颗粒物中多环芳烃的测定　高效液相色谱法 HJ 647 11 二噁英类 环境空气和废气　二噁英类的测定　同位素稀释高分辨气相色谱-高分辨质谱法 HJ/T 77.2 12 沥青烟 固定污染源排气中沥青烟的测定　重量法 HJ/T 45 5.2　大气污染物基准氧含量排放浓度折算方法 实测的大气污染物排放浓度，应按表3和公式（1）折算为基准氧含量排放浓度。国家和山东省规定了行业单位产品基准排气量的，按单位产品基准排气量进行折算。 表3　基准氧含量 序号 装置类型 基准氧含量（O2）% 1 炼焦化学工业 焦炉烟囱 8 2 石油化学工业 工艺加热炉、有机废气焚烧装置 3 3 石油炼制工业 工艺加热炉、催化再生、酸性气回收装置及有机废气焚烧装置 3 4 合成树脂工业 有机废气焚烧装置 3 5 炭素行业 焙烧炉和煅烧炉 15 6 钛白粉厂 回转窑 15 7 无机化学工业 氧化态炉窑 8 还原态炉窑 5 8 烧碱、聚氯乙烯工业 废气焚烧装置 3 9 冲天炉 冷风炉（鼓风温度≤400 ℃） 15 热风炉（鼓风温度＞400 ℃） 12 10 金属熔炼炉、烧结炉、炉窑干燥尾气以及非焚烧类有机废气排放口 在国家、省规定基准氧含量前，暂按实测浓度计 11 其他工业炉窑 9 (1) 式中： c ——大气污染物基准氧含量排放浓度，mg/m3； c’——实测的大气污染物排放浓度，mg/m3； O2’——实测的氧含量，%； O2 ——基准氧含量，%。 6　达标判定 6.1　各级生态环境部门按照相关手工监测技术规范获取的监测结果超过本标准排放浓度限值的，判定为排放超标。各级生态环境部门在对企业进行监督性检查时，可以将现场即时采样或监测的结果，作为判定排污行为是否符合排放标准以及实施相关环境保护管理措施的依据。 6.2　特殊工况下的达标判定按国家有关规定执行。 7　实施与监督 本标准实施后，新制（修）订的国家或山东省排放标准中大气污染物的排放限值，通过审批、审核或备案的环境影响评价文件，排污许可证中相应大气污染物的排放要求严于本标准的，相应大气污染物按从严要求执行。 _________________________________