标准编号:	T/CNCI 01005-2018
中文名称:	低 VOCs 含量高固体分、超高固体分和无溶剂环氧涂料定义
英文名称:	Definition of low VOCs content high solids, ultra high solids and solvent-free epoxy coating
行业分类:	T/    团体标准
发布日期:	2018-05-01
实施日期:	2018-7-1
标准状态:	valid
翻译语言:	英文
文件格式:	PDF
中文字符数:	7000 字
翻译价格(元):	490.0
交付时间:	付款后 1 个工作日

Codeofchina.com is in charge of this English translation. In case of any doubt about the English translation, the Chinese original shall be considered authoritative. This standard is developed in accordance with the rules given in GB/T 1.1-2009. This standard was proposed by China National Coatings Industry Association. This standard is under the jurisdiction of China National Coatings Industry Association Standardization. Definition of low VOCs content high solids, ultra high solids and solvent-free epoxy coating 1 Scope This standard specifies the terms and definitions, requirements, test methods, inspection rules, marking, labeling, packaging and storage of low VOCs content high solids, ultra high solids and solvent-free epoxy coating. This standard is applicable to low VOCs content high solids, ultra high solids and solvent-free epoxy coating used in the field of industrial anti-corrosion. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. GB/T 1725 Paints varnishes and plastics - Determination of non-volatile-matter content GB/T 3186 Paints varnishes and raw materials for paints and varnishes - Sampling GB/T 8170 Rules of rounding off for numerical values & expression and judgment of limiting values GB/T 9272-2007 Paints and varnishes - Determination of percentage volume of non-volatile matter by measuring the density of a dried coating GB/T 9278 Temperatures and humidities for conditioning and testing of paint specimens GB/T 9750 Marks for package of coating products GB/T 13491 General rule for packing of coatings GB/T 21862.4-2008 Paints and varnishes - Determination of density - Part 4: Pressure cup method GB/T 23985-2009 Paints and varnishes - Determination of volatile organic compound (VOC) content - Difference method GB/T 23986-2009 Paints and varnishes - Determination of volatile organic compound (VOC) content - Gas-chromatographic method 3 Terms and definitions For the purpose of this document, the following terms and definitions apply. 3.1 industrial anti-corrosive epoxy coating two-component liquid coating with epoxy resin or modified epoxy resin as main film-forming material, which is mainly used for the protection of steel structures in industries such as ship, bridge, infrastructure, petrochemical and energy 3.2 high solids epoxy coating solvent-based epoxy coating with the non-volatile matter by volume of 70%~85% and the volatile organic compounds content less than 250g/L measured under standard application condition according to the specified method 3.3 ultra high solids epoxy coating solvent-based epoxy coating with the non-volatile matter greater than 88% and the volatile organic compounds content less than 150g/L measured under standard application condition according to the specified method 3.4 solvent-free epoxy coating epoxy coating with the non-volatile matter greater than 97% and the volatile organic compounds content less than 60g/L measured under standard application condition according to the specified method 3.5 non-volatile matter by volume, NVv volume percentage of residue obtained after volatilization under specified condition 3.6 non-volatile matter, NV residue (by mass) obtained after volatilization under specified condition 3.7 standard application condition state in which application may also be carried out given that VOCs range still meets the requirements of the corresponding products in Table 1 at 25℃, irrespective of adding diluent, where the application method and condition meet the requirements in the technical specifications of those products 3.8 volatile organic compounds, VOCs any organic liquid or solid that may evaporate naturally at normal temperature and pressure of the atmospheric environment where it is present Note 1: for the term VOCs currently used in the coating field, see volatile organic compounds (VOCs) content. Note 2: as specified in U.S. government regulations, the term VOCs is limited to those compounds with photochemical activity in the atmosphere (see ASTM D3960), while any other compounds are defined as exempt compounds. [See ISO 4618: 2006] Note 3: as specified in European regulations such as European Union directive 2004/42/EC, the term VOCs refers to the volatile organic compounds with boiling points up to 250℃ under 101.325kPa of standard pressure. 3.9 volatile organic compounds content, VOCs content content of volatile organic compounds measured in the coatings under specified condition Note 1: the property and quantity of compound to be considered depend on the application field of coating. For each application field, the determination or calculation method and the limit are specified by laws or agreed by both parties. [See ISO 4618: 2006] Note 2: if the term VOCs refers to compounds defined with the highest boiling point, the compounds with boiling points lower than the limit are taken as VOCs content, while those with boiling points higher than the limit are taken as non-volatile organic compounds. 4 Requirements High solids, ultra high solids and solvent-free epoxy coating shall meet the requirements of Table 1.   Table 1 Requirements Classification NVv/% NV/% VOCs content/(g/L) Suggested test items NVv NV VOCs content High solids epoxy coating ≥70 ≥80 <250 √ — √ Ultra high solids epoxy coating ≥85 ≥88 <150 — √ √ Solvent-free epoxy coating ≥95 ≥97 <60 — √ √ Note 1: at present, NVv method is generally used to calculate for high solids epoxy coating, while the NV method should be used to calculate for ultra high solids epoxy coating and solvent-free coating to obtain the consistent test result of NVv and VOCs content. Note 2: the NV of high solids epoxy coating, and the NVv of ultra high solids epoxy and solvent-free epoxy coating are optional test indexes (not compulsory). Note 3: the NVv and VOCs content of high solids epoxy coating must meet the requirements of corresponding class at the same time before it is defined according to its class. Note 4: the NV and VOCs content of ultra high solids epoxy and solvent-free epoxy coating must meet the requirements of corresponding classes at the same time before they are defined according to their classes.

Foreword i 1 Scope 2 Normative references 3 Terms and definitions 4 Requirements 5 Test methods 6 Inspection rules 7 Marking, labeling, packaging and storage

ICS 87.040 CCS G50 团体标准 T/CNCIA 01005-2018 低 VOCs含量高固体分、超高固体分和无溶 剂环氧涂料定义 Definition of low VOCs content high solids, ultra high solids and solvent-free epoxy coating 2018-05-01 发布 2018-07-01 实施 中国涂料工业协会 发布 前言 本标准依据GB/T 1.1-2009给出的规则起草。 本标准由中国涂料工业协会提出。 本标准由中国涂料工业协会标准化委员会归口。 本标准主要起草单位：中远佐敦船舶涂料有限公司、 低 VOCs 含量高固体分、超高固体分和无溶剂环氧涂料定义 1 范围 本标准规定了低VOCs含量高固体分、超高固体分和无溶剂环氧涂料的术语和定义、要求、试验方法、检验规则、标识、标签、包装和贮存。 本标准适用于工业防腐领域使用低VOCs含量高固体分、超高固体分和无溶剂环氧涂料。 2 规范性引用文件 下列文件对于本文件的应用是必不可少的。凡是注日期的引用文件，仅所注日期的版本适用于本文件。凡是不注日期的引用文件，其最新版本（包括所有的修改单）适用于本文件。 GB/T 1725 色漆、清漆和塑料 不挥发物含量的测定 GB/T 3186 色漆、清漆和色漆与清漆用原材料 取样 GB/T 8170 数值修约规则与极限数值的表示和判定 GB/T 9272—2007 体积分数色漆和清漆 通过测量干涂层密度测定涂料的不挥发物体积分数 GB/T 9278 涂料试样状态调节和试验的温湿度 GB/T 9750 涂料产品包装标志 GB/T 13491 涂料产品包装通则 GB/T 21862.4—2008 色漆和清漆 密度的测定 第4部分：压杯法 GB/T 23985—2009 色漆和清漆 挥发性有机化合物(VOC)含量的测定 差值法 GB/T 23986—2009 色漆和清漆 挥发性有机化合物(VOC)含量的测定 气相色谱法 3 术语与定义 下列术语和定义适用于本文件。 3.1 工业防腐环氧涂料 industrial anti-corrosive epoxy coating 以环氧树脂或改性环氧树脂为主要成膜材料的双组分液体涂料。主要用于船舶、桥梁、基建、石化、能源等行业钢结构的保护。 3.2 高固体分环氧涂料 high solids epoxy coating 按规定的方法测得标准施工状态下的不挥发物体积分数为70%~85%，且挥发性有机化合物含量小于250g/L的溶剂型环氧涂料。 3.3 超高固体分环氧涂料 ultra high solids epoxy coating 按规定的方法测得的标准施工状态下的不挥发物质量分数大于88%，且挥发性有机化合物含量小于150g/L的溶剂型环氧涂料。 3.4 无溶剂环氧涂料 solvent-free epoxy coating 按规定的方法测得的标准施工状态下的不挥发物质量分数大于97%，且挥发性有机化合物含量小于60g/L的环氧涂料。 3.5 不挥发物体积分数 non-volatile matter by volume, NVv 在规定条件下，经挥发后所得到的残余物的体积百分数。 3.6 不挥发物质量分数 non- volatile matter, NV 在规定条件下，经挥发后所得到的残余物（按质量计）。 3.7 标准施工状态 standard application condition 25℃条件下，在施工方式和施工条件满足相应产品技术说明书中的要求时，不添加稀释剂或添加稀释剂后VOCs范围仍符合表1中对应产品所列要求时，仍可进行施工的状态。 3.8 挥发性有机化合物 volatile organic compounds, VOCs 在所处大气环境的正常温度和压力下，可以自然蒸发的任何有机液体或固体。 注1：目前涂料领域所使用的术语VOCs，参见挥发性有机化合物含量（VOCs含量）。 注2：美国政府法规中规定，术语VOCs仅限于指那些在大气中具有光化学活性的化合物（见ASTM D3960），而任何其他的化合物被定义为豁免化合物。 [见ISO 4618：2006] 注3：欧洲法规如欧盟指令2004/42/EC中规定，术语VOCs是指在101.325kPa标准压力下，沸点最高可达250℃的挥发性有机化合物。 3.9 挥发性有机化合物（VOCs）含量 volatile organic compounds content, VOCs content 在规定条件下，所测得的涂料中存在的挥发性有机化合物得含量。 注1：所需考虑的化合物的性质和数量将取决于涂料应用的领域。对于每个应用领域来说，测定或计算的方法以及限量值是通过法规规定或双方约定。 [见ISO 4618：2006] 注2：如果术语VOCs是指以最高沸点定义的化合物，则将沸点低于限定值的化合物看作为VOCs含量的部分，而沸点高于该限定值的化合物看作为非挥发性有机化合物。 4 要求 高固体分、超高固体分和无溶剂环氧涂料产品应符合表 1 的要求。 表 1 要求 分类 不挥发物 体积分数 /% 不挥发物 质量分数 /% VOCs含量 /(g/L) 建议检测项目 不挥发物体 积分数 不挥发物 质量分数 VOCs 含量 高固体分环氧涂料 ≥70 ≥80 <250 √ — √ 超高固体分环氧涂料 ≥85 ≥88 <150 — √ √ 无溶剂环氧涂料 ≥95 ≥97 <60 — √ √ 注1：目前对于高固体分环氧涂料通常采用不挥发物体积分数的方法计算，但对于超高固体分环氧涂料和无溶剂涂料，为得到不挥发物体积分数和VOCs含量一致性的测试结果，宜采用不挥发物质量分数的方法计算。 注2：高固体分环氧涂料的不挥发物质量分数，超高固体分环氧涂料和无溶剂环氧涂料的不挥发物体积分数为选择性测试指标，非强制要求。 注3：高固体分环氧涂料的不挥发物体积分数和VOCs含量必须同时满足对应分类的要求，方可按其分类定义。 注4：超高固体分环氧涂料和无溶剂环氧涂料的不挥发物质量分数和VOCs含量必须同时满足对应分类的要求，方可按其分类定义。 5 试验方法 5.1 取样 按GB/T 3186规定取样，也可以按商定的方法取样，取样量根据试验需要确定。 5.2 试验环境 产品应在（23±2）℃，相对湿度（50±5）%条件下放置24h后进行性能测试和样板制备。除另有规定外，试板的状态调节和试验的温湿度应符合GB/T 9278的规定。 5.3 不挥发物体积分数 按GB/T 9272—2007中7.2.3板片法的规定进行。其中液体涂料密度的测定按照该标准中所规定的GB/T 21862.4-2008 压力比重杯法测量。 注：因为高固体分、超高固体分和无溶剂环氧涂料内气泡含量的影响，所以用压力比重杯测试。 5.4 不挥发物质量分数 高固体分环氧涂料、超高固体分环氧涂料和无溶剂环氧涂料的不挥发物质量分数按表2的规定进行测试。 表 2 不挥发物质量分数测试方法 编号 分类 测试方法 1 高固体分环氧涂料a 将主剂和固化剂按比例混合均匀后立即称量，取样量（2±0.2）g。称量好的试样可在（23±2）℃和环境大气压下放置1h，按GB/T1725规定进行测试。 试验条件：（105±2）℃/1h。 2 超高固体分环氧涂料 将主剂和固化剂按比例混合均匀后立即称量，称样量为（2±0.2）g。称量好的试样在（23±2）℃和环境大气压下放置24h后，按GB/T 1725规定进行测试。 试验条件：（105±2）℃/1h。 3 无溶剂环氧涂料 a 如试验样品在加热过程中会发生任何异常分解或降解，经有关方商定后，试样可在（23±2）℃和环境大气压下放置24h后测试。 5.5 挥发性有机化合物含量 按GB/T23985—2009中8.3或GB/T23986—2009中10.3规定进行。 6 检验规则 6.1 检验分类 6.1.1 产品检验分为出厂检验和型式检验。 6.1.2 型式检验项目包括本标准所列的全部要求，在正常生产的情况下，对于高固体分环氧涂料和超高固体分环氧涂料及无溶剂环氧涂料，本标准中表1所规定的项目，每两年进行一次。 6.2 检验结果的判定 6.2.1 检验结果的判定按 GB/T 8170 数值修约值比较法进行。 6.2.2 应检项目的检验结果均达到本标准要求时，则判定该样品符合本标准要求。 7 标志、标签、包装和贮存 7.1 标志 标志应符合GB/T 9750的要求。 7.2 标签 涂料包装容器应附有标签，注明产品的标准号、型号、名称、质量、批号、贮存期、生产厂名、厂址及生产日期。 7.3 包装 包装应符合GB/T 13491中一级包装的要求。 7.4 贮存 贮存时应保证通风，干燥，防止阳光直接照射并应隔离火源，远离热源。产品应根据类型定出贮存期，并在包装标志上明示。