标准编号:	GB/T 5750.9-2023
中文名称:	生活饮用水标准检验方法 第9部分：农药指标
英文名称:	Standard examination methods for drinking water—Part 9: Pesticides indices
中标分类:	C51    环境卫生
行业分类:	GB    国家标准
ICS分类:	13.060 13.060     13.060
发布机构:	国家市场监督管理总局 国家标准化管理委员会
发布日期:	2023-03-17
实施日期:	2023-10-1
标准状态:	valid
替代旧标准:	GB/T 5750.9-2006 生活饮用水标准检验方法 农药指标
翻译语言:	英文
文件格式:	PDF
中文字符数:	65000 字
翻译价格(元):	5800.0
交付时间:	付款后 1~8 个工作日

Foreword This document is drafted in accordance with the provisions of GB/T 1.1-2020 "Guidelines for Standardization Work Part 1 Structure and starting rules for standardized documents This document is GB/T 5750 "Standard Test Methods for Drinking Water" Part 9. GB/T 5750 has issued the following parts Part 1: General Provisions. Part 2: the collection and preservation of water samples Part 3: Quality control of water quality analysis. Part 4: sensory properties and physical indicators Part 5: inorganic non-metallic indicators. Part 6: metal and metal-like indicators Part 7: organic composite indicators. Part 8: organic indicators. Part 9: Pesticide indicators. Part 10: Disinfection by-product indicators. Part 11: Disinfectant indicators. Part 12: Microbiological indicators. Part 13: Radioactive indicators This document replaces GB/T 5750.9-2006 "Standard Test Methods for Drinking Water Pesticide Indicators" compared with GB/T 5750.9-2006, in addition to structural adjustments and editorial changes, the main technical changes are as follows. a) increased the "terms and definitions" (see Chapter 3). b) the addition of nine test methods (see 8,3,12,2,13,4,14,2,21,2,25.1,36,1,36.2,41.1); c) the deletion of five test methods (see the 2006 version of 1.14.19.111.111.2). Please note that some of the contents of this document may involve patents. The issuing agency of this document does not assume responsibility for identifying patents This document was proposed and attributed by the National Health and Wellness Commission of the People's Republic of China. Introduction GB/T 5750 "Standard Test Methods for Drinking Water" as the recommended national standard for drinking water testing technology and GB 5749 "Drinking Water Sanitation Standards" supporting the important technical support of GB 5749, for the implementation of GB 5749, to carry out health and safety assessment of drinking water to provide test methods. GB / T 5750 consists of 13 parts. Part 1: General Provisions. The purpose is to provide the basic principles and requirements of water quality testing. Part 2: the collection and preservation of water samples. The purpose is to provide water samples collected, preservation, management, transport and sampling quality control of the basic principles, measures and requirements. Part 3: quality control of water quality analysis. The purpose is to provide water quality inspection and testing laboratory quality control requirements and methods Part 4: Sensory traits and physical indicators. The purpose is to provide sensory traits and physical indicators of the corresponding test methods Part 5: inorganic non-metallic indicators. The purpose is to provide inorganic non-metallic indicators of the corresponding test methods Part 6: Metals and metal-like indicators. The purpose is to provide metal and metal-like indicators of the corresponding test methods Part 7: Organic composite indicators. The purpose is to provide a comprehensive index of organic substances corresponding test methods Part 8: organic indicators. The purpose is to provide the corresponding test methods for organic indicators. Part 9: Pesticide indicators. The purpose is to provide the corresponding test methods for pesticide indicators. Part 10: Disinfection by-products indicators. The purpose is to provide the corresponding test methods for disinfection by-product indicators Part 11: Disinfectant indicators. The purpose is to provide the corresponding test methods for disinfectant indicators Part 12: Microbiological indicators. The purpose is to provide the corresponding test methods for microbial indicators Part 13: radioactive indicators. The purpose is to provide the corresponding test methods for radioactive indicators 1 Scope This document describes the domestic drinking water in DDT, six-six-six, lindane, parathion, methyl parathion, endosulfan, malathion, leuconazole, chlorothalonil, acephate, acephate vinegar, methomyl, 2,4-dichlorodiphenyl, coagulantan, poisonous cicada, coupons gozin, oxaliplatin, heptachlor, hexachlorobenzene, pentachlorophenol, fluorobenzoic vein, fluorfen dolphin, deltamethrin vein, fluorin yard vein, fluorobellic vein, chlorpyrifos vein, fluoropropoxy vein Diquat, chlorfenvinphos-methyl coolamide, liguron, metolachlor, chlorfenvinphos-methyl, methomyl cool, cyhalothrin vinegar, cyhalothrin, chlorfenvinphos-methyl, ethephon in water sources and the determination of DDT (capillary column gas chromatography), hexachlorobenzene, lindane (capillary column gas chromatography), parathion (capillary column gas chromatography), methyl parathion (capillary column gas chromatography), endosulfan, malathion ( capillary column gas chromatography), Ralston (capillary column gas chromatography), methomyl (high-pressure liquid chromatography-UV detector, spectrophotometry, high-pressure liquid chromatography-fluorescence detector), methomyl (liquid-liquid extraction gas chromatography), 24-drop (liquid-liquid extraction gas chromatography) diquat (capillary column gas chromatography) Dan (high performance liquid chromatography) poisonous death (liquid-liquid extraction gas chromatography), hidrozine (high performance liquid chromatography), Gan (high performance liquid chromatography) chlorine (liquid-liquid extraction gas chromatography) pentachlorophenol (derivatization gas chromatography, headspace solid-phase microtake gas chromatography) determination method This document applies to the determination of pesticide indicators in drinking water and (or) water source water 2 Normative reference documents The following documents constitute the essential provisions of this document through the normative references in the text. Among them, note the date of the reference document, only the date of the corresponding version applies to this document; do not note the date of the reference document, its latest version (including all the revision of the single) applies to this document. GB/T 5750.1 Standard test methods for drinking water Part 1: General Provisions GB/T 5750.3 Standard test methods for drinking water Part 3: Quality control of water quality analysis GB/T 5750.8-2023 Standard test methods for drinking water Part 8: organic matter indicators GB/T 5750.10-2023 Standard test methods for drinking water part 10: disinfection by-products indicators GB/ T6682 Analytical laboratory water specifications and test methods 3 Terms and definitions GB/T 5750.1GB/T 5750.3 defined terms and definitions apply to this document 4 DDT 4.1 Capillary column gas chromatography 4.1.1 Minimum detection mass concentration 5 solid-phase extraction gas chromatography-mass spectrometry Determination by the method described in GB/T 5750.8-2023 15.1 6Luxin Capillary column gas chromatography:Determination according to the method described in 4.1 6 Lindane Capillary column gas chromatography 6.1 Determination by the method described in 4.1 6.2 Solid phase extraction gas chromatography mass spectrometry Determination by the method described in 15.1 of GB/T 5750.8-2023 7 Parathion Capillary column gas chromatography 7.1 7.1.1 Minimum detectable mass concentration The minimum detectable mass of this method are: dichlorvos, 0.012ng; methomyl, 0.025ng; endosulfan, 0.025ng; leuconazole 0.025ng; methyl parathion, 0.025ng; malathion, 0,025ng; parathion, 0.025ng. If 250mL of water sample is taken after extraction, the minimum detectable mass concentrations are: dichlorvos. 0.05g/L; methomyl, 0.1g/L; endosulfan, 0.1g/L; leuconazole, 0.1g/L; methyl parathion, 0.1ug/L; malathion, 0.1ug/L; parathion, 0.1g/L. 7.1.2 Principle Trace organic phosphorus in water by dichloromethane extraction, concentration, quantitative injection into the chromatograph, each organic phosphorus in the column one by one separation, in turn in the flame photometric detector hydrogen-rich flame combustion, the emission of 526n wavelength of the characteristic light. The intensity of light is proportional to the amount of phosphorus contained, and this characteristic light is passed through a filter and detected by a photomultiplier tube for quantitative analysis. 8 Methyl parathion 8.1 Capillary column gas chromatography Determination by the method described in 7.1 8.2 solid-phase extraction gas chromatography-mass spectrometry Determination by GB/T 5750.8-2023 in the method described in 15.1 8.3 Liquid chromatography tandem mass spectrometry 8.3.1 Minimum detection mass concentration The minimum detectable masses of this method are as follows: nortriptyline, 0.002 ng; mantan, 0.003 ng; methyl parathion, 0.004 ng. When 20 l. water samples are directly injected for determination, the minimum detectable mass concentrations are as follows: nortriptyline, 0.10 g/L; mantan, 0.15 g/L; methyl parathion 0.20ug/L. The common coexisting ions and compounds in the water do not interfere with the determination of the 3 compounds This method is only used for the determination of domestic drinking water 8.3.2 Principle The water sample is filtered through a needle-type microporous membrane and fed directly into the sample, and detected by liquid chromatography tandem mass spectrometry with multiple reaction monitoring (MKM) method for the determination of 3 pesticides in domestic drinking water, namely aldicarb, atrazine and methyl parathion, and quantified by external standard method. 9 Internal absorption of phosphorus Capillary column gas chromatography: according to the method described in 7.1 to determine 10 Malathion 10.1 Capillary column gas chromatography Determination by the method described in 7.1 10.2 Solid phase extraction gas chromatography mass spectrometry Determination by the method described in 15.1 of GB/T 5750.8-2023 11 Loctite 11.1 Capillary column gas chromatography Determination according to the method described in 7.1 11.2 solid phase extraction gas chromatography mass spectrometry Determination by the method described in 15.1 of GB/T 5750.8-2023 12 Chlorothalonil 12.1 Solid-phase extraction gas chromatography-mass spectrometry Determination by the method described in GB/T 5750.8-2023 15.1 12.2 Capillary column gas chromatography 12.2.1 Minimum detection mass concentration The minimum detection mass of this method is 0.006ng, if 500L water samples are taken after treatment, the minimum detection mass concentration is 0.12ug / L. This method is only used for the determination of domestic drinking water. 13 methamphetamine 13.1 high performance liquid chromatography a - UV detector 13.1.1 Minimum detection mass concentration The minimum detection mass of this method is 2ng, if the 100mL water sample is taken to determine the minimum detection mass concentration of 0.01mg/L.,, 14 Ao cyanothrin vinegar 14.1 Solid phase extraction gas chromatography mass spectrometry Determination according to the method described in 15.1 of GB/T 5750.8-2023 15 Methoprene 15.1 Liquid-liquid extraction gas chromatography 15.1.1 Minimum detectable mass concentration The minimum detectable masses of this method are: methoprene, 0.1ng; 2,4-drops, 0.03ng. If a water sample of 00mL is taken after treatment, the minimum detectable mass concentrations are: methoprene, 0.5ug/L; 2,4-drops, .15ug/L.

Foreword Introduction 1 Scope 2 Normative reference documents 3 Terms and definitions 4 DDT 5 solid-phase extraction gas chromatography-mass spectrometry 6Luxin 6 Lindane 7 Parathion 8 Methyl parathion 9 Internal absorption of phosphorus 10 Malathion 11 Loctite 12 Chlorothalonil 13 methamphetamine 14 Ao cyanothrin vinegar 15 Methoprene

前言 本文件按照GB/T 1.1-2020《标准化工作导则 第1部分标准化文件的结构和起规则》的规定起草 本文件是GB/T 5750《生活饮用水标准检验方法》的第9部分。GB/T 5750已经发布了以下部分第1部分:总则; 第2部分:水样的采集与保存 第3部分:水质分析质量控制; 第4部分:感官性状和物理指标 第5部分:无机非金属指标; 第6部分:金属和类金属指标 第7部分:有机物综合指标; 第8部分:有机物指标: 第9部分:农药指标; 第10部分:消毒副产物指标; 第11部分:消毒剂指标; 第12部分:微生物指标; 第13部分:放射性指标 本文件代替GB/T 5750.9-2006《生活饮用水标准检验方法农药指标》与GB/T 5750.9-2006相比,除结构调整和编辑性改动外，主要技术变化如下: a)增加了“术语和定义”(见第3章): b)增加了9个检验方法(见8,3,12,2,13,4,14,2、21,2、25.1,36,1,36.2、41.1);c)删除了5个检验方法(见2006年版的1.14.19.111.111.2)。 请注意本文件的某些内容可能涉及专利。本文件的发布机构不承担识别专利的责任本文件由中华人民共和国国家卫生健康委员会提出并归口。 引言 GB/T 5750《生活饮用水标准检验方法》作为生活饮用水检验技术的推荐性国家标准与GB 5749《生活饮用水卫生标准》配套,是GB 5749的重要技术支撑,为贯彻实施GB 5749,开展生活饮用水卫生安全性评价提供检验方法。 GB/T 5750由13个部分构成。 第1部分:总则。目的在于提供水质检验的基本原则和要求。 第2部分:水样的采集与保存。目的在于提供水样采集、保存、管理、运输和采样质量控制的基本原则、措施和要求。 第3部分:水质分析质量控制。目的在于提供水质检验检测实验室质量控制要求与方法 第4部分:感官性状和物理指标。目的在于提供感官性状和物理指标的相应检验方法 第5部分:无机非金属指标。目的在于提供无机非金属指标的相应检验方法 第6部分:金属和类金属指标。目的在于提供金属和类金属指标的相应检验方法 第7部分:有机物综合指标。目的在于提供有机物综合指标的相应检验方法 第8部分:有机物指标。目的在于提供有机物指标的相应检验方法。 第9部分:农药指标。目的在于提供农药指标的相应检验方法。 第10部分:消毒副产物指标。目的在于提供消毒副产物指标的相应检验方法 第11部分:消毒剂指标。目的在于提供消毒剂指标的相应检验方法 第12部分:微生物指标。目的在于提供微生物指标的相应检验方法 第13部分:放射性指标。目的在于提供放射性指标的相应检验方法 1范围 本文件描述了生活饮用水中滴滴涕、六六六、林丹、对硫磷、甲基对硫磷、内吸磷、马拉硫磷、乐果、百菌清、甲茶威、澳氰菊醋、灭草松、2,4-滴、敌敌畏、哄喃丹、毒死蝉、券去津、草甘腾、七氯、六氯苯、五氯酚、氟苯脉、氟虫豚、除虫脉、氟院脉、氟铃脉、杀铃脉、氟丙氧脉、敌草隆、氯虫苯甲酷胺、利谷隆、甲氧隆、氯硝柳胺、甲氰菊酷、氯氟氰菊醋、氰戊菊、氯菊酷、乙草胺的测定方法和水源水中滴滴涕(毛细管柱气相色谱法)、六六六、林丹(毛细管柱气相色谱法)、对硫磷(毛细管柱气相色谱法)、甲基对硫磷(毛细管柱气相色谱法)、内吸磷、马拉硫磷(毛细管柱气相色谱法)、乐果(毛细管柱气相色谱法)、甲茶威(高压液相色谱法-紫外检测器、分光光度法、高压液相色谱法-荧光检测器)、灭草松(液液取气相色谱法)、24-滴(液液取气相色谱法)敌敌(毛细管气相色谱法)丹(高效液相色谱法)毒死(液液取气相色谱法)、秀去津(高效液相色谱法)、甘牌(高效液相色谱法)氯(液液取气相色谱法)五氯酚(衍生化气相色谱法、顶空固相微取气相色谱法)的测定方法 本文件适用于生活饮用水和(或)水源水中农药指标的测定 2规范性引用文件 下列文件中的内容通过文中的规范性引用而构成本文件必不可少的条款。其中,注日期的引用文件,仅该日期对应的版本适用于本文件;不注日期的引用文件,其最新版本(包括所有的修改单)适用于本文件。 GB/T 5750.1生活饮用水标准检验方法第1部分:总则 GB/T 5750.3生活饮用水标准检验方法第3部分:水质分析质量控制 GB/T 5750.8-2023生活饮用水标准检验方法第8部分:有机物指标 GB/T 5750.10-2023生活饮用水标准检验方法第10部分:消毒副产物指标 GB/T6682分析实验室用水规格和试验方法 3术语和定义 GB/T 5750.1GB/T 5750.3界定的术语和定义适用于本文件 4滴滴涕 4.1毛细管柱气相色谱法 4.1.1最低检测质量浓度 5固相萃取气相色谱质谱法 按GB/T 5750.8-2023中15.1描述的方法测定 6六六六 毛细管柱气相色谱法:按4.1描述的方法测定 6林丹 毛细管柱气相色谱法6.1 按4.1描述的方法测定 6.2固相萃取气相色谱质谱法 按GB/T 5750.8-2023中15.1描述的方法测定 7对硫磷 毛细管柱气相色谱法7.1 7.1.1最低检测质量浓度 本方法最低检测质量分别为:敌敌畏,0.012ng;甲拌磷,0.025ng;内吸磷,0.025ng;乐果0.025ng;甲基对硫磷,0.025ng;马拉硫磷,0,025ng;对硫磷,0.025ng。若取250mL水样萃取后测定则最低检测质量浓度分别为:敌敌畏,0.05g/L;甲拌磷,0.1g/L;内吸磷,0.1g/L;乐果,0.1g/L;甲基对硫磷,0.1ug/L;马拉硫磷,0.1ug/L;对硫磷,0.1g/L。 7.1.2原理 水中微量有机磷经二氯甲烷萃取、浓缩,定量注入色谱仪,各有机磷在色谱柱上逐一分离，依次在火焰光度检测器富氢火焰中燃烧,发射出526n波长的特征光。光强度与含磷量成正比，此特征光通过滤光片,由光电倍增管检测进行定量分析。 8甲基对硫磷 8.1毛细管柱气相色谱法 按7.1描述的方法测定 8.2固相萃取气相色谱质谱法 按GB/T 5750.8-2023中15.1描述的方法测定 8.3液相色谱串联质谱法 8.3.1最低检测质量浓度 本方法最低检测质量分别为:去津,0.002ng;味喃丹,0.003ng;甲基对硫磷,0.004ng。取20l.水样直接进样测定时,最低检测质量浓度分别为:秀去津,0.10g/L;喃丹,0.15g/L;甲基对硫磷0.20ug/L。 水中常见共存离子及化合物均不干扰该3种化合物的测定 本方法仅用于生活饮用水的测定 8.3.2原理 水样经针式微孔滤膜过滤后直接进样，以液相色谱串联质谱的多反应监测(MKM)方式检测生活饮用水中味喃丹、萎去津和甲基对硫磷3种农药，外标法定量。 9内吸磷 毛细管柱气相色谱法:按7.1描述的方法测定 10马拉硫磷 10.1毛细管柱气相色谱法 按7.1描述的方法测定 10.2固相萃取气相色谱质谱法 按GB/T 5750.8-2023中15.1描述的方法测定 11乐果 11.1毛细管柱气相色谱法 按7.1描述的方法测定 11.2固相萃取气相色谱质谱法 按GB/T 5750.8-2023中15.1描述的方法测定 12百菌清 12.1固相萃取气相色谱质谱法 按GB/T 5750.8-2023中15.1描述的方法测定 12.2毛细管柱气相色谱法 12.2.1最低检测质量浓度 本方法最低检测质量为0.006ng，若取500L水样经过处理后测定则最低检测质量浓度为0.12ug/L。 本方法仅用于生活饮用水的测定。 13甲威 13.1高效液相色谱法一-紫外检测器 13.1.1最低检测质量浓度 本方法最低检测质量为2ng,若取100mL水样测定则最低检测质量浓度为0.01mg/L。、 14澳氰菊醋 14.1固相萃取气相色谱质谱法 按GB/T 5750.8-2023中15.1描述的方法测定 15灭草松 15.1液液萃取气相色谱法 15.1.1最低检测质量浓度 本方法最低检测质量分别为:灭草松,0.1ng;2,4-滴,0.03ng。若取水样00mL经处理后测定，则最低检测质量浓度分别为:灭草松,0.5ug/L;2,4-滴,.15ug/L。