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Codeofchina.com is in charge of this English translation. In case of any doubt about the English translation, the Chinese original shall be considered authoritative. This standard is developed in accordance with the rules given in GB/T 1.1-2009. This standard replaces GB 24330-2009 General security technical specification for domestic sanitary insecticide. The following main technical changes have been made with respect to GB 24330-2009: ——The normative references of the standard are modified (see Clause 2; Clause 2 of Edition 2009); ——The requirements for the content of active ingredients and the allowable fluctuation range are modified (see Table 1; Table 1 of Edition 2009); ——The requirements for the efficacy are modified (see 4.4; 4.4 of Edition 2009); ——The requirements for heat storage stability are modified (see 4.5; 4.5 of Edition 2009); ——The requirements for the minimum effective period of liquid vaporizer are modified (see 4.7; 4.7 of Edition 2009); ——The requirements for methyl alcohol content in aerosols insecticide are modified (see 4.8); ——The requirements for hygiene indexes of repellent products are added (see 4.12); ——The safety requirements of clothing mothproofer products are added (see 4.13); ——The test methods for the content of active ingredients and allowable fluctuation range are modified (see 5.3; 5.3 of Edition 2009); ——The requirements for the efficacy are modified (see 5.4; 5.4 of Edition 2009); ——The test method for the heat storage stability is modified (see 5.5; 5.5 of Edition 2009); ——The test method for the smoke dust is modified (see 5.6; 5.6 of Edition 2009); ——The test method for the minimum effective period of liquid vaporizer is modified (see 5.7; 5.7 of Edition 2009); ——The test method for the methyl alcohol content in aerosols insecticide is added (see 5.9); ——The test method for the net content of aerosols insecticide is modified (see 5.11; 5.10 of Edition 2009); ——The test method for hygiene indexes of repellent products is added (see 5.13); ——The test method for the safety of clothing mothproofer products is added (see 5.14); ——The test methods for the content of active ingredients in Annex A, Annex B, Annex C and Annex D are modified; ——The test method for the smoke dust of mosquito coil is deleted (Annex E of Edition 2009); ——The determination methods for the contents of p-dichlorobenzene, o-dichlorobenzene and m-dichlorobenzene are added (see Annex E); ——The test method for the naphthalene (a clothing mothproofer) is added (see Annex F). Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. The issuing body of this document shall not be held responsible for identifying any or all such patent rights. This standard was proposed by and is under the jurisdiction of the Ministry of Industry and Information Technology of the People's Republic of China. The previous edition of this standard is as follows: ——GB 24330-2009. General security technical specification for domestic sanitary insecticide 1 Scope This standard specifies the general security requirements and test methods for domestic sanitary insecticide in terms of personal health, environmental protection and other aspects. This standard is applicable to domestic sanitary insecticide for controlling mosquitoes, flies, cockroaches and other pests. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated reference, only the edition cited applies. For undated references, the latest edition of the referenced documents (including any amendments) applies. GB/T 13917.1 Laboratory efficacy test methods and criterions of public health insecticides for pesticide registration - Part 1: Spray fluid GB/T 13917.2 Laboratory efficacy test methods and criterions of public health insecticides for pesticide registration - Part 2: Aerosol GB/T 13917.3 Laboratory efficacy test methods and criterions of public health insecticides for pesticide registration - Part 3: Smoke generator and smoke tablet GB/T 13917.4 Laboratory efficacy test methods and criterions of public health insecticides for pesticide registration - Part 4: Mosquito coil GB/T 13917.5 Laboratory efficacy test methods and criterions of public health insecticides for pesticide registration - Part 5: Vaporizing mat GB/T 13917.6 Laboratory efficacy test methods and criterions of public health insecticides for pesticide registration - Part 6: Liquid vaporizer GB/T 13917.7 Laboratory efficacy test methods and criterions of public health insecticides for pesticide registration - Part 7: Bait GB/T 13917.8 Laboratory efficacy test methods and criterions of public health insecticides for pesticide registration - Part 8: Dutsable powder and chalk GB/T 13917.9 Laboratory efficacy test methods and criterions of public health insecticides for pesticide registration - Part 9: Repellent GB/T 28015 Domestic sanitary insecticide - Test method of smoke dust NY/T 1151.1-2015 Laboratory efficacy test methods and criterions of public health insecticides for pesticide registration - Part 1: Mothproofing agent QB/T 4147 Repellent floral water QB/T 4148 Domestic sanitary insecticide of cockroach bait QB/T 4149 Domestic sanitary insecticide of cockroach bait gel QB/T 4150 Domestic sanitary insecticide of cockroach bait coil Measures for the metrological supervision and administration of quantitatively packed commodities (Decree No.75 of the General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China) Safety and Technical Standards for Cosmetics (Edition 2015) 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1 active ingredient chemical components having biological insecticidal activity 3.2 efficacy insects (including flies, cockroaches, ants, etc.) controlling (killing) performance of product under specified conditions and within specified time 3.3 median knockdown time KT50 time required for 50% of the tested insects to be knocked down under the specified conditions 3.4 minimum effective period minimum effective time when liquid vaporizer is used together with electric heater 4 Requirements 4.1 Requirements for the use of active ingredients Agentia allowed to be used shall be registered according to the provisions of the state department concerned. 4.2 Toxicology It shall meet the toxicological evaluation requirements of corresponding formulation stipulated by the state department concerned. 4.3 Content of active ingredients and allowable fluctuation range 4.3.1 The content of active ingredients shall be clearly indicated on the product packaging. 4.3.2 See Table 1 for the allowable fluctuation range of the content of active ingredients. Table 1 Type of product Allowable fluctuation range Smoke preparations such as mosquito coil, cockroach bait coil, line incense and light mosquito coil -20%X~40%X Liquid vaporizer product -10%X~25%X Vaporizing mat and pyrethroid mothproofing tablets -10%X~35%X Other formulations X≤1 -15%X~35%X 1 Note: X is the indicated content of active ingredient, which is expressed in %, mg/tablet or g/100mL respectively. Select based on the content of active ingredients in different formulation. a The unit of a value is consistent with the content of corresponding active ingredient, X. 4.4 Efficacy 4.4.1 Mosquito coils and line incense KT50≤8.0min. 4.4.2 Vaporizing mat KT50≤8.0min. 4.4.3 Liquid vaporizer KT50≤8.0min. 4.4.4 Aerosols insecticide See Table 2 for the efficacy of aerosols insecticide. The death time of mosquitoes and flies is 24h, and that of cockroaches is 72h. Table 2 Tested insect KT50 min Death rate % Mosquito ≤5.0 ≥95 Fly ≤5.0 ≥95 Cockroach ≤9.0 ≥95 Note: When the product is indicated for specific insects, the efficacy may only be tested for indicated insects. 4.4.5 Spray fluid, smoke generator and smoke tablet, bait, dutsable powder, chalk, repellent, clothing mothproofer. 4.4.5.1 See Table 3 for the efficacy of spray fluid, smoke generator and smoke tablet, bait, dutsable powder and chalk. Table 3 Formulation Subject Dose mL/m3 Observation time KT50 min Death rate % Spray fluid Oil base class Mosquito 0.714 3 — ≤5.0 ≥95.0 Fly 0.714 3 — ≤6.0 ≥95.0 Cockroach 7.143 — ≤10.0 ≥95.0 Water and alcohol classes Mosquito 1.43 — ≤10.0 ≥95.0 Fly 1.43 — ≤10.0 ≥95.0 Cockroach 7.143 — ≤15.0 ≥95.0 Missible oil Mosquito 1.43 — ≤10.0 ≥90.0 Fly 1.43 — ≤10.0 ≥90.0 Cockroach 7.143 — ≤15.0 ≥90.0 Smoke generator and smoke tablet Mosquito — — — ≥95.0 Fly — — — ≥95.0 Cockroach — — — ≥85.0 Bait formulation Cockroach — 12d after bait casting — ≥ 90.0 Ant — 7d after bait casting — ≥ 90.0 Fly — 24h after bait casting — ≥ 90.0 Dutsable powder and chalk Cockroach — — — ≥95.0 Ant — — — ≥95.0 Flea — — — ≥95.0 4.4.5.2 The effective protection time of natural plant repellent products is greater than or equal to 2.0h, and that of chemical synthetic repellent products is greater than or equal to 4.0h. 4.4.5.3 The efficacy of the clothing mothproofer shall meet the requirements of NY/T 1151.1-2015. 4.4.6 Other formulations of products They shall meet the technical requirements of relevant national standards. 4.5 Heat storage stability For the product having subjected to the heat storage stability test, the degradation rate of the active ingredient content of p-dichlorobenzene clothing mothproofer is less than or equal to 5%, that of the active ingredient content of pyrethroid is less than or equal to 10%, and that of other active ingredient content is less than or equal to 15%. 4.6 Smoke dust 4.6.1 The classification of smoke-free and slightly smoked mosquito coil and line incense products shall be clearly indicated on the product packaging. 4.6.2 The smoke dust shall meet the requirements of Table 4. Table 4 In mg/g Product classification Smoke dust Smoke free ≤5 Slightly smoked ≤30 4.7 Minimum effective period The liquid vaporizer shall be marked with the minimum effective period (in h), and after conducting the test specified in 5.7, the liquid in the bottle shall be in contact with the core rod. 4.8 Methyl alcohol content in aerosols insecticide Methyl alcohol content ≤2 000mg/kg (water-based and alcohol-based types only). 4.9 Internal pressure of aerosols insecticide The internal pressure of aerosol insecticide is ≤ 1.0MPa. Note: For the aerosols insecticide product equipped with a quantitative valve for an amount of below 50mL, the internal pressure will not be measured. 4.10 Net content of aerosols insecticide It shall be clearly indicated on the tank body and marked with volume or mass unit. The deviation shall meet the requirements in attached Table 3 of Measures for the metrological supervision and administration of quantitatively packed commodities. 4.11 Net content of other formulations It shall be clearly indicated on the product or package, marked with volume or mass unit. The deviation shall meet the requirements in attached Table 3 of Measures for the metrological supervision and administration of quantitatively packed commodities. 4.12 Hygienic indexes of repellent products See Table 5 for hygienic indexes of repellent products that are in direct contact with human body. Table 5 In mg/kg Item Index Methyl alcohol ≤2 000 Lead ≤10 Arsenic ≤2 Mercury ≤1 Cadmium ≤5 4.13 Safety requirements of clothing mothproofer products Naphthalene shall not be detected from clothing mothproofer products. 5 Test method 5.1 Requirements for the use of active ingredients Check whether there is a registration certificate for drug usage. 5.2 Toxicology Provide the toxicological test report of the corresponding formulation in the “Provisions on pesticide registration data”. 5.3 Content of active ingredients and allowable fluctuation range 5.3.1 Check whether the content of active ingredients is clearly indicated on the product packaging. 5.3.2 The contents of active ingredients in mosquito coil, vaporizing mat, liquid vaporizer, aerosols insecticide and p-dichlorobenzene clothing mothproofer are tested according to those specified in Annex A, Annex B, Annex C, Annex D and Annex E respectively. 5.3.3 The contents of active ingredients in other formulations shall be tested according to the methods specified in QB/T 4147, QB/T 4148, QB/T 4149, QB/T 4150 or other corresponding standards. 5.4 Efficacy Clothing mothproofers are tested according to NY/T 1151.1, the efficacy of other formulations is tested according to the methods specified in GB/T 13917.1 ~ 13917.9 or other corresponding standards, and the efficacy of mosquito coil, line incense, vaporizing mat, liquid vaporizer and aerosols insecticide products is tested by cylinder method. 5.5 Heat storage stability 5.5.1 Apparatus 5.5.1.1 Thermostat (or thermostatic water bath): (54±2)℃. 5.5.1.2 Ampoule bottle (or glass bottle with stopper that can be sealed at 54℃): 50mL. 5.5.1.3 Explosion-proof oven: control the temperature at (54±2)℃. 5.5.1.4 Balance: with a division value of not less than 0.01g. 5.5.2 Test steps of mosquito coil After crushing the middle coil of a box of test samples, pass it through a 0.154mm (100 meshes/in) standard sorting sieve, put one half into an ampoule bottle and seal the bottle (the other half is used for determining the content of active ingredients), then put it in a thermostat at (54±2)℃ for 14d. After taking out the samples, test the content of active ingredients and calculate the degradation rate within 24h according to Annex A. 5.5.3 Test steps of vaporizing mat Take the vaporizing mat in the same column of sealing bag (along the long side direction of vaporizing mat) as sample to determine the content of active ingredients before and after heat storage. Place the heat-stored samples (with packaging) in a thermostat at (54±2)℃ for 14d, after taking out the samples, test the content of active ingredients and calculate the degradation rate within 24h according to Annex B. 5.5.4 Test steps of liquid vaporizer Take out a part of test sample from a bottle for determining the content of active ingredients, put the rest into an ampoule bottle and seal the bottle, then put it in a thermostat at (54±2)℃ for 14d. After taking out the sample, test the content of active ingredients and calculate the degradation rate within 24h according to Annex C. 5.5.5 Test steps of aerosols insecticide Place the whole bottle of the test sample in an explosion-proof oven at (54±2)℃ for 14d. After taking out the sample, test the content of active ingredients and calculate the degradation rate within 24h according to Annex D. 5.5.6 Test steps of clothing mothproofer Place the test sample of pyrethroid clothing mothproofer (with packaging) in a thermostat at (54±2)℃ for 14d. After taking out the sample, test the content of active ingredients and calculate the degradation rate within 24h according to Annex B. Place a whole bag of test samples of p-dichlorobenzene clothing mothproofer in a thermostat at (54±2)℃ for 14d. After taking out the sample, test the content of active ingredients and calculate the degradation rate within 24h according to Annex E. 5.5.7 Degradation rate of active ingredients It shall be calculated using Equation (1): (1) where, P——the degradation rate, %; m1——the content of active ingredients in the sample measured before heat storage; m2——the content of active ingredients in the sample measured after heat storage. 5.5.8 Result judgment If the degradation rate is rejected, a second test can be carried out for the sampled product from the same batch. If it is still rejected, this Item shall be judged as rejected. 5.5.9 Other formulations of products They shall be tested according to the test methods in relevant national standards. 5.6 Smoke dust The smoke dust shall be tested according to the method specified in GB/T 28015. 5.7 Minimum effective period of liquid vaporizer It is tested in the temperature of (23±3)℃, with relative humidity of (65±15)%, and no strong convection air. (Test angle) unscrew the bottle cap of the liquid vaporizer, conduct the test by electrifying continuously (the liquid bottle is connected with a matching electric heater), and perform visual inspection until reaching the indicated minimum effective period, and observe whether the liquid contained in the bottle is in contact with the core rod to ensure that the product can be used longer than the minimum effective period. Test at least 3 bottles in parallel, and take the average of the effective period. Foreword i 1 Scope 2 Normative references 3 Terms and definitions 4 Requirements 5 Test method Annex A (Normative) Determination of the content of active ingredients of mosquito coil Annex B (Normative) Determination of the content of active ingredients of vaporizing mat/pyrethroid clothing mothproofer Annex C (Normative) Determination of the content of active ingredients of liquid vaporizer Annex D (Normative) Determination method of active ingredients in aerosols insecticide Annex E (Normative) Determination method of p-dichlorobenzene, o-dichlorobenzene and m-dichlorobenzene content Annex F (Normative) Test method of naphthalene in clothing mothproofer ICS 65.100.10 G 25 GB 中华人民共和国国家标准 GB 24330—2020 代替GB 24330—2009 ________________________________________________________________________ 家用卫生杀虫用品安全通用技术条件 General security technical specification for domestic sanitary insecticide 2020-12-24发布 2022-01-01实施 国家市场监督管理总局 国家标准化管理委员会 发布 前言 本标准按照GB/T 1.1—2009给出的规则起草。 本标准代替GB 24330—2009《家用卫生杀虫用品安全通用技术条件》，与GB 24330—2009相比，除编辑性修改外，主要技术变化如下： ——修改了标准的规范性引用文件(见第2章，2009年版的第2章)； ——修改了有效成分含量及允许波动范围的要求(见表1，2009年版的表1)； ——修改了药效的要求(见4.4，2009年版的4.4)； ——修改了热贮稳定性的要求(见4.5，2009年版的4.5)； ——修改了电热蚊香液最低持效期的要求(见4.7，2009年版的4.7)； ——增加了杀虫气雾剂中甲醇含量的要求(见4.8)； ——增加了驱避类产品卫生指标的要求(见4.12)； ——增加了衣物防蛀剂产品安全要求(见4.13)； ——修改了有效成分含量及允许波动范围的试验方法(见5.3，2009年版的5.3)； ——修改了药效的试验方法(见5.4，2009年版的5.4)； ——修改了热贮稳定性的试验方法(见5.5，2009年版的5.5)； ——修改了烟尘量的测试方法(见5.6，2009年版的5.6)； ——修改了电热蚊香液最低持效期的试验方法(见5.7，2009年版的5.7)； ——增加了杀虫气雾剂中甲醇含量的测试方法(见5.9)； ——修改了杀虫气雾剂净含量的测试方法(见5.11，2009年版的5.10) ——增加了驱避类产品卫生指标的测试方法(见5.13)； ——增加了衣物防蛀剂产品安全的测试方法(见5.14)； ——修改了附录A、附录B、附录C、附录D的有效成分含量测试方法； ——删除了蚊香烟尘量测试方法(2009年版的附录E)； ——增加了对二氯苯、邻二氯苯、间二氯苯含量的测定方法(见附录E)； ——增加了衣物防蛀剂萘的测试方法(见附录F)。 请注意本文件的某些内容可能涉及专利。本文件的发布机构不承担识别这些专利的责任。 本标准由中华人民共和国工业和信息化部提出并归口。 本标准所代替标准的历次版本发布情况为： ——GB 24330—2009。 家用卫生杀虫用品安全通用技术条件 1 范围 本标准规定了家用卫生杀虫用品类产品有关人身健康、环境保护等方面的安全通用要求及试验方法。 本标准适用于用于家庭防治蚊、蝇、蜚蠊等虫害的卫生杀虫用品。 2 规范性引用文件 下列文件对于本文件的应用是必不可少的。凡是注日期的引用文件，仅注日期的版本适用于本文件。凡是不注日期的引用文件，其最新版本(包括所有的修改单)适用于本文件。 GB/T 13917.1 农药登记用卫生杀虫剂室内药效试验及评价 第1部分：喷射剂 GB/T 13917.2 农药登记用卫生杀虫剂室内药效试验及评价 第2部分：气雾剂 GB/T 13917.3 农药登记用卫生杀虫剂室内药效试验及评价 第3部分：烟剂及烟片 GB/T 13917.4 农药登记用卫生杀虫剂室内药效试验及评价 第4部分：蚊香 GB/T 13917.5 农药登记用卫生杀虫剂室内药效试验及评价 第5部分：电热蚊香片 GB/T 13917.6 农药登记用卫生杀虫剂室内药效试验及评价 第6部分：电热蚊香液 GB/T 13917.7 农药登记用卫生杀虫剂室内药效试验及评价 第7部分：饵剂 GB/T 13917.8 农药登记用卫生杀虫剂室内药效试验及评价 第8部分：粉剂、笔剂 GB/T 13917.9 农药登记用卫生杀虫剂室内药效试验及评价 第9部分：驱避剂 GB/T 28015 家用卫生杀虫用品 烟尘量试验方法 NY/T 1151.1—2015 农药登记用卫生杀虫剂室内药效试验及评价 第1部分：防蛀剂 QB/T 4147 驱蚊花露水 QB/T 4148 家用卫生杀虫用品 杀蟑饵剂 QB/T 4149 家用卫生杀虫用品 杀蟑胶饵 QB/T 4150 家用卫生杀虫用品 蟑香 定量包装商品计量监督管理办法(国家质量监督检验检疫总局令第75号) 化妆品安全技术规范(2015版) 3 术语和定义 下列术语和定义适用于本文件。 3.1 有效成分 active ingredient 具有生物杀虫活性的化学成分。 3.2 药效 efficacy 产品在规定的条件下及规定的时间内，能够达到的驱(灭)蚊虫(包括蝇、蜚蠊、蚂蚁等)效果。 3.3 击倒中时 median knockdown time KT50 在规定的条件下，50％的试虫被击倒(即仰倒)所需的时间。 3.4 最低持效期 minimum effective period 电热蚊香液与电加热器配套使用时可以达到的最低有效时间。 4 要求 4.1 有效成分使用要求 应按照国家有关部门规定进行登记允许使用的药剂。 4.2 毒理 符合国家有关部门规定的相应剂型的毒理学评价要求。 4.3 有效成分含量及允许波动范围 4.3.1 有效成分含量应在产品包装上明示。 4.3.2 有效成分含量允许波动范围见表1。 表1 产品剂型 允许波动范围 蚊香、蟑香、线香、轻质蚊香等烟制剂产品 —20％X～40％X 电热蚊香液产品 —10％X～25％X 电热蚊香片及拟除虫菊酯防蛀片剂产品 —10％X～35％X 其他剂型 X≤1 —15％X～35％X 1＜X≤2.5 ±25％X 2.5＜X≤10 ±10％X 10＜X≤25 ±6％X 25＜X≤50 ±5％X X＞50 ±2.5a 注：X为明示有效成分含量，分别以％、mg/片或g/100 mL为单位。根据不同剂型的有效成分含量标识进行选择。 a 该数值的单位与对应的有效成分含量X一致。 4.4 药效 4.4.1 蚊香、线香 KT50≤8.0 min。 4.4.2 电热蚊香片 KT50≤8.0 min。 4.4.3 电热蚊香液 KT50≤8.0 min。 4.4.4 杀虫气雾剂 杀虫气雾剂药效见表2。其中，蚊、蝇死亡率时间为24 h，蜚蠊死亡率时间为72 h。 表2 试虫 KT50 min 死亡率 ％ 蚊 ≤5.0 ≥95 蝇 ≤5.0 ≥95 蜚蠊 ≤9.0 ≥95 注：产品明示特定昆虫时，仅对明示昆虫进行药效试验。 4.4.5 喷射剂、烟剂及烟片、饵剂、粉剂、笔剂、驱避类、衣物防蛀剂 4.4.5.1 喷射剂、烟剂及烟片、饵剂、粉剂、笔剂药效见表3。 表3 剂型 对象 剂量mL/m3 观察时间 KT50 min 死亡率 ％ 喷射剂 油基类 蚊 — — ≤5.0 ≥95.0 蝇 — — ≤6.0 ≥95.0 蜚蠊 — — ≤10.0 ≥95.0 水基和醇基类 蚊 — — ≤10.0 ≥95.0 蝇 — — ≤10.0 ≥95.0 蜚蠊 — — ≤15.0 ≥95.0 乳油 蚊 — — ≤10.0 ≥90.0 蝇 — — ≤10.0 ≥90.0 蜚蠊 — — ≤15.0 ≥90.0 烟剂及烟片 蚊 — — — ≥95.0 蝇 — — — ≥95.0 蜚蠊 — — — ≥85.0 饵剂 蜚蠊 — 投饵后12 d — ≥90.0 蚂蚁 — 投饵后7 d — ≥90.0 蝇 — 投饵后24 h — ≥90.0 粉剂、笔剂 蜚蠊 — — — ≥95.0 蚂蚁 — — — ≥95.0 蚤 — — — ≥95.0 4.4.5.2 天然植物驱避类产品有效保护时间≥2.0 h，化学合成驱避类产品有效保护时间≥4.0 h。 4.4.5.3 衣物防蛀剂的药效规定应符合NY/T 1151.1—2015的要求。 4.4.6 其他剂型产品 按国家相关标准中的技术要求执行。 4.5 热贮稳定性 产品经热贮稳定性试验后，对二氯苯衣物防蛀剂有效成分含量的降解率≤5％，菊酯类有效成分含量的降解率≤10％，其他类有效成分含量的降解率≤15％。 4.6 烟尘量 4.6.1 无烟、微烟的蚊香、线香类产品分类应在产品包装上明示。 4.6.2 烟尘量应符合表4的要求。 表4 单位为毫克每克 产品分类 烟尘量 无烟 ≤5 微烟 ≤30 4.7 最低持效期 电热蚊香液应标明最低持效期(以h表示)，经5.7试验后，瓶内药液应与芯棒接触。 4.8 杀虫气雾剂中甲醇含量 甲醇含量≤2 000 mg/kg(仅限水基和醇基)。 4.9 杀虫气雾剂内压 杀虫气雾剂内压值≤1.0 MPa。 注：50 mL以下定量阀门的杀虫气雾剂产品不测内压。 4.10 杀虫气雾剂净含量 应明示在罐体上，用容积或质量单位标注。其偏差应符合《定量包装商品计量监督管理办法》中附表3相应规定。 4.11 其他剂型产品的净含量 应明示在产品或包装上，用容积或质量单位标注。其偏差应符合《定量包装商品计量监督管理办法》中附表3相应规定。 4.12 驱避类产品卫生指标 与人体直接接触的驱避类产品卫生指标见表5。 表5 单位为毫克每千克 项目 指标 甲醇 ≤2 000 铅 ≤10 砷 ≤2 汞 ≤1 镉 ≤5 4.13 衣物防蛀剂产品安全要求 衣物防蛀剂产品中萘不得检出。 5 试验方法 5.1 有效成分使用要求 检查是否有用药的登记证书。 5.2 毒理 提供“农药登记资料规定”中相应剂型的毒理学试验报告。 5.3 有效成分含量及允许波动范围 5.3.1 检查产品包装上是否明示有效成分含量。 5.3.2 蚊香、电热蚊香片、电热蚊香液、杀虫气雾剂、对二氯苯衣物防蛀剂的有效成分含量分别按附录A、附录B、附录C、附录D、附录E进行测试。 5.3.3 其他剂型产品的有效成分含量按QB/T 4147、QB/T 4148、QB/T 4149、QB/T 4150或其他相应标准中规定的方法进行测试。 5.4 药效 衣物防蛀剂按NY/T 1151.1进行检测，其他剂型产品的药效按GB/T 13917.1～13917.9或其他相应标准中规定的方法进行检测，蚊香、线香、电热蚊香片、电热蚊香液和杀虫气雾剂产品的药效检测选用圆筒法。 5.5 热贮稳定性 5.5.1 仪器 5.5.1.1 恒温箱(或恒温水浴)：(54±2)℃。 5.5.1.2 安瓿瓶(或在54℃下，仍能密封的具塞玻璃瓶)：50 mL。 5.5.1.3 防爆烘箱：控温(54±2)℃。 5.5.1.4 天平：分度值不低于0.01 g。 5.5.2 蚊香测试步骤 一盒试验样品中取中间的一盘粉碎后，过0.154 mm(100目/in)标准分样筛，取其一半放到安瓿瓶中密封(另一半做有效成分含量测试)，然后放置在(54±2)℃的恒温箱内14 d，取出试样后于24 h内按附录A进行有效成分含量测试并计算降解率。 5.5.3 电热蚊香片测试步骤 选取位于蚊香片密封袋同一列(蚊香片长边方向)的样品，用于测试热贮前后有效成分含量，将热贮样品(带包装)放置在(54±2)℃的恒温箱内14 d，取出后于24 h内按附录B进行有效成分含量测试并计算降解率。 5.5.4 电热蚊香液测试步骤 将一瓶测试样品先取出一部分做有效成分含量，剩余部分放到安瓿瓶中密封，再放置在(54±2)℃的恒温箱内14 d，取出试样后于24 h内按附录C进行有效成分含量测试并计算降解率。 5.5.5 杀虫气雾剂测试步骤 试验样品整瓶放置在(54±2)℃的防爆烘箱内14 d，取出试样后于24 h内按附录D进行有效成分含量测试并计算降解率。 5.5.6 衣物防蛀剂测试步骤 将拟除虫菊酯衣物防蛀剂试验样品(带包装)放置在(54±2)℃的恒温箱内14 d，取出试样后于24 h内按附录B进行有效成分含量测试并计算降解率。 将对二氯苯衣物防蛀剂试验样品整袋放置在(54±2)℃的恒温箱内14 d，取出试样后于24 h内按附录E进行有效成分含量测试并计算降解率。 5.5.7 有效成分的降解率 按式(1)进行计算。 (1) 式中： P——降解率，％； m1——热贮前测出的样品有效成分含量； m2——热贮后测出的样品有效成分含量。 5.5.8 结果判定 降解率不合格，可在同批抽样产品中进行二次测试。如仍不合格，则该项判定为不合格。 5.5.9 其他剂型产品 按国家相关标准中的试验方法执行。 5.6 烟尘量 烟尘量按GB/T 28015的方法进行检测。 5.7 电热蚊香液最低持效期 在温度(23±3)℃、相对湿度(65±15)％的条件下，无强对流空气的环境下测试。(测试角)旋开药液瓶盖，连续通电进行试验(药液瓶与配套的电加热器连接)，目测直至达到其明示最低持效期时，观察瓶内装有的药液与芯棒是否接触以确保产品高于最低持效期的使用。平行测试至少3瓶，取其持效期平均值。 5.8 电热蚊香液净含量 在温度(23±3)℃，相对湿度为(65±15)％条件下，药液倒入量筒或用天平称量，读出测试值(量筒分度值：0.1 mL；天平分度值：0.1 g)。 5.9 杀虫气雾剂中甲醇含量 在试管中直接喷出试样，按《化妆品安全技术规范(2015版)》第四章2.22规定的方法进行测定甲醇含量。 5.10 杀虫气雾剂内压 5.10.1 仪器 5.10.1.1 压力表：量程0 MPa～1.6 MPa，精度2.5级，带专用接头。 5.10.1.2 计时器。 5.10.1.3 恒温水浴锅：控温精度±2℃。 5.10.2 测试步骤 按产品说明的要求正确按压阀门的促动器，排除滞留在阀门和吸管中的空气，然后将试样置于(55±2)℃的水浴中，使水浸至罐身高度的五分之四处，恒温30 min。戴厚皮手套，取出试样迅速擦干。拔掉阀门的促动器，将压力表进口对准阀杆，用力压紧，待压力表指针稳定后，记下压力表读数。以三次测量的最大值为准。 5.11 杀虫气雾剂净含量 5.11.1 以质量为计量单位的杀虫气雾剂净含量 以整罐产品作为样品，称其质量，记为m3。然后按产品标示的喷射方法喷出内容物，直到喷不出内容物为止，再将气雾剂开罐，将罐体内壁的残留物清洗干净，烘干称其质量，记为m4。按式(2)计算产品的净含量。 W1＝m3—m4 (2) 式中： W1——以质量为计量单位的杀虫气雾剂净含量，单位为克(g)； m3——整罐样品质量，单位为克(g)； m4——空罐及构件质量，单位为克(g)。 5.11.2 以体积为计量单位的杀虫气雾剂净含量 5.11.2.1 仪器 5.11.2.1.1 带刻度的玻璃气雾剂试管：体积90 mL，最小分度值1 mL。 5.11.2.1.2 天平：分度值不低于0.01 g。 5.11.2.2 试验温度 试验温度为(23±3)℃。 5.11.2.3 测试步骤 采用无吸管的阀门装配好玻璃气雾剂试管，将玻璃气雾剂试管擦拭干净，先注入抛射剂约10 mL，再将抛射剂喷空，称其质量，记录为m5。 以整罐产品作为样品，称其质量，用于计算其以质量为计量单位的净含量。将样品充分摇匀，通过一截长约8mm、内径略大于试样阀杆直径的塑料管(可采用气雾剂阀门吸管)，将样品和玻璃气雾剂试管的阀杆对接起来。将样品与玻璃气雾剂试管水平放置(见图1)，适当用力挤压，尽可能迅速地将样品内容物注入玻璃气雾剂试管中。如注入的内容物为气相，则将样品与玻璃气雾剂进行旋转，直至转注入的内容物为液相。当注入的内容物约占玻璃气雾剂试管容积的65％～75％时，停止挤压，取下样品，称取此时玻璃气雾剂的试管质量m6。将玻璃试管气雾剂置于(25±3)℃的环境中约45 min，待其中的内容物液面稳定后，读取内容物的体积，记为V1。按照5.11.1中方法喷空样品内容物，测定其以质量为计量单位的净含量m7。 玻璃气雾剂试管 塑料管 试样 图1 以体积为计量单位的杀虫气雾剂净含量测定装置 5.11.2.4 结果的计算 按式(3)计算每支试样的净含量。 (3) 式中： V2——以体积为计量单位的杀虫气雾剂净含量，单位为毫升(mL)； m7——以质量为计量单位的样品净含量，单位为克(g)； m6——注入样品内容物后的玻璃气雾剂试管的质量，单位为克(g)； m5——待注入样品内容物的玻璃气雾剂试管的质量，单位为克(g)； V1——导入玻璃气雾剂管中的内容物体积，单位为毫升(mL)。 5.11.2.5 结果判定 以体积为计量单位的杀虫气雾剂净含量不合格，可在同批抽样产品中进行二次测试。如仍不合格，则该项判定为不合格。 5.12 其他剂型产品的净含量 5.12.1 以质量为计量单位的其他剂型产品净含量 将试样称其质量，然后去尽内容物，洗净烘干，称取皮重，按式(4)计算净含量。 W2＝m8—m9 (4) 式中： W2——以质量为计量单位的其他剂型产品净含量，单位为克(g)； m8——毛重，单位为克(g)； m9——皮重，单位为克(g)。 5.12.2 以体积为计量单位的其他剂型产品净含量 药液倒入量筒(量筒分度值为1 mL)测量，读出测试值。 5.13 驱避类产品卫生指标 驱避类产品的汞含量、砷含量、铅含量、镉含量以及涂抹类的驱避剂产品甲醇含量按《化妆品安全技术规范(2015版)》中第四章相关的理化检验方法进行测定。 5.14 衣物防蛀剂产品安全要求 按附录F的方法进行测定。 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