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This standard is developed in accordance with the rules given in GB/T 1.1-2009.
This standard replaces GB 24330-2009 General security technical specification for domestic sanitary insecticide. The following main technical changes have been made with respect to GB 24330-2009:
——The normative references of the standard are modified (see Clause 2; Clause 2 of Edition 2009);
——The requirements for the content of active ingredients and the allowable fluctuation range are modified (see Table 1; Table 1 of Edition 2009);
——The requirements for the efficacy are modified (see 4.4; 4.4 of Edition 2009);
——The requirements for heat storage stability are modified (see 4.5; 4.5 of Edition 2009);
——The requirements for the minimum effective period of liquid vaporizer are modified (see 4.7; 4.7 of Edition 2009);
——The requirements for methyl alcohol content in aerosols insecticide are modified (see 4.8);
——The requirements for hygiene indexes of repellent products are added (see 4.12);
——The safety requirements of clothing mothproofer products are added (see 4.13);
——The test methods for the content of active ingredients and allowable fluctuation range are modified (see 5.3; 5.3 of Edition 2009);
——The requirements for the efficacy are modified (see 5.4; 5.4 of Edition 2009);
——The test method for the heat storage stability is modified (see 5.5; 5.5 of Edition 2009);
——The test method for the smoke dust is modified (see 5.6; 5.6 of Edition 2009);
——The test method for the minimum effective period of liquid vaporizer is modified (see 5.7; 5.7 of Edition 2009);
——The test method for the methyl alcohol content in aerosols insecticide is added (see 5.9);
——The test method for the net content of aerosols insecticide is modified (see 5.11; 5.10 of Edition 2009);
——The test method for hygiene indexes of repellent products is added (see 5.13);
——The test method for the safety of clothing mothproofer products is added (see 5.14);
——The test methods for the content of active ingredients in Annex A, Annex B, Annex C and Annex D are modified;
——The test method for the smoke dust of mosquito coil is deleted (Annex E of Edition 2009);
——The determination methods for the contents of p-dichlorobenzene, o-dichlorobenzene and m-dichlorobenzene are added (see Annex E);
——The test method for the naphthalene (a clothing mothproofer) is added (see Annex F).
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. The issuing body of this document shall not be held responsible for identifying any or all such patent rights.
This standard was proposed by and is under the jurisdiction of the Ministry of Industry and Information Technology of the People's Republic of China.
The previous edition of this standard is as follows:
——GB 24330-2009.
General security technical specification for domestic sanitary insecticide
1 Scope
This standard specifies the general security requirements and test methods for domestic sanitary insecticide in terms of personal health, environmental protection and other aspects.
This standard is applicable to domestic sanitary insecticide for controlling mosquitoes, flies, cockroaches and other pests.
2 Normative references
The following referenced documents are indispensable for the application of this document. For dated reference, only the edition cited applies. For undated references, the latest edition of the referenced documents (including any amendments) applies.
GB/T 13917.1 Laboratory efficacy test methods and criterions of public health insecticides for pesticide registration - Part 1: Spray fluid
GB/T 13917.2 Laboratory efficacy test methods and criterions of public health insecticides for pesticide registration - Part 2: Aerosol
GB/T 13917.3 Laboratory efficacy test methods and criterions of public health insecticides for pesticide registration - Part 3: Smoke generator and smoke tablet
GB/T 13917.4 Laboratory efficacy test methods and criterions of public health insecticides for pesticide registration - Part 4: Mosquito coil
GB/T 13917.5 Laboratory efficacy test methods and criterions of public health insecticides for pesticide registration - Part 5: Vaporizing mat
GB/T 13917.6 Laboratory efficacy test methods and criterions of public health insecticides for pesticide registration - Part 6: Liquid vaporizer
GB/T 13917.7 Laboratory efficacy test methods and criterions of public health insecticides for pesticide registration - Part 7: Bait
GB/T 13917.8 Laboratory efficacy test methods and criterions of public health insecticides for pesticide registration - Part 8: Dutsable powder and chalk
GB/T 13917.9 Laboratory efficacy test methods and criterions of public health insecticides for pesticide registration - Part 9: Repellent
GB/T 28015 Domestic sanitary insecticide - Test method of smoke dust
NY/T 1151.1-2015 Laboratory efficacy test methods and criterions of public health insecticides for pesticide registration - Part 1: Mothproofing agent
QB/T 4147 Repellent floral water
QB/T 4148 Domestic sanitary insecticide of cockroach bait
QB/T 4149 Domestic sanitary insecticide of cockroach bait gel
QB/T 4150 Domestic sanitary insecticide of cockroach bait coil
Measures for the metrological supervision and administration of quantitatively packed commodities (Decree No.75 of the General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China)
Safety and Technical Standards for Cosmetics (Edition 2015)
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
3.1
active ingredient
chemical components having biological insecticidal activity
3.2
efficacy
insects (including flies, cockroaches, ants, etc.) controlling (killing) performance of product under specified conditions and within specified time
3.3
median knockdown time
KT50
time required for 50% of the tested insects to be knocked down under the specified conditions
3.4
minimum effective period
minimum effective time when liquid vaporizer is used together with electric heater
4 Requirements
4.1 Requirements for the use of active ingredients
Agentia allowed to be used shall be registered according to the provisions of the state department concerned.
4.2 Toxicology
It shall meet the toxicological evaluation requirements of corresponding formulation stipulated by the state department concerned.
4.3 Content of active ingredients and allowable fluctuation range
4.3.1 The content of active ingredients shall be clearly indicated on the product packaging.
4.3.2 See Table 1 for the allowable fluctuation range of the content of active ingredients.
Table 1
Type of product Allowable fluctuation range
Smoke preparations such as mosquito coil, cockroach bait coil, line incense and light mosquito coil -20%X~40%X
Liquid vaporizer product -10%X~25%X
Vaporizing mat and pyrethroid mothproofing tablets -10%X~35%X
Other formulations X≤1 -15%X~35%X
150 ±2.5a
Note: X is the indicated content of active ingredient, which is expressed in %, mg/tablet or g/100mL respectively. Select based on the content of active ingredients in different formulation.
a The unit of a value is consistent with the content of corresponding active ingredient, X.
4.4 Efficacy
4.4.1 Mosquito coils and line incense
KT50≤8.0min.
4.4.2 Vaporizing mat
KT50≤8.0min.
4.4.3 Liquid vaporizer
KT50≤8.0min.
4.4.4 Aerosols insecticide
See Table 2 for the efficacy of aerosols insecticide. The death time of mosquitoes and flies is 24h, and that of cockroaches is 72h.
Table 2
Tested insect KT50
min Death rate
%
Mosquito ≤5.0 ≥95
Fly ≤5.0 ≥95
Cockroach ≤9.0 ≥95
Note: When the product is indicated for specific insects, the efficacy may only be tested for indicated insects.
4.4.5 Spray fluid, smoke generator and smoke tablet, bait, dutsable powder, chalk, repellent, clothing mothproofer.
4.4.5.1 See Table 3 for the efficacy of spray fluid, smoke generator and smoke tablet, bait, dutsable powder and chalk.
Table 3
Formulation Subject Dose mL/m3 Observation time KT50
min Death rate
%
Spray fluid Oil base class Mosquito 0.714 3 — ≤5.0 ≥95.0
Fly 0.714 3 — ≤6.0 ≥95.0
Cockroach 7.143 — ≤10.0 ≥95.0
Water and alcohol classes Mosquito 1.43 — ≤10.0 ≥95.0
Fly 1.43 — ≤10.0 ≥95.0
Cockroach 7.143 — ≤15.0 ≥95.0
Missible oil Mosquito 1.43 — ≤10.0 ≥90.0
Fly 1.43 — ≤10.0 ≥90.0
Cockroach 7.143 — ≤15.0 ≥90.0
Smoke generator and smoke tablet Mosquito — — — ≥95.0
Fly — — — ≥95.0
Cockroach — — — ≥85.0
Bait formulation Cockroach — 12d after bait casting — ≥ 90.0
Ant — 7d after bait casting — ≥ 90.0
Fly — 24h after bait casting — ≥ 90.0
Dutsable powder and chalk Cockroach — — — ≥95.0
Ant — — — ≥95.0
Flea — — — ≥95.0
4.4.5.2 The effective protection time of natural plant repellent products is greater than or equal to 2.0h, and that of chemical synthetic repellent products is greater than or equal to 4.0h.
4.4.5.3 The efficacy of the clothing mothproofer shall meet the requirements of NY/T 1151.1-2015.
4.4.6 Other formulations of products
They shall meet the technical requirements of relevant national standards.
4.5 Heat storage stability
For the product having subjected to the heat storage stability test, the degradation rate of the active ingredient content of p-dichlorobenzene clothing mothproofer is less than or equal to 5%, that of the active ingredient content of pyrethroid is less than or equal to 10%, and that of other active ingredient content is less than or equal to 15%.
4.6 Smoke dust
4.6.1 The classification of smoke-free and slightly smoked mosquito coil and line incense products shall be clearly indicated on the product packaging.
4.6.2 The smoke dust shall meet the requirements of Table 4.
Table 4 In mg/g
Product classification Smoke dust
Smoke free ≤5
Slightly smoked ≤30
4.7 Minimum effective period
The liquid vaporizer shall be marked with the minimum effective period (in h), and after conducting the test specified in 5.7, the liquid in the bottle shall be in contact with the core rod.
4.8 Methyl alcohol content in aerosols insecticide
Methyl alcohol content ≤2 000mg/kg (water-based and alcohol-based types only).
4.9 Internal pressure of aerosols insecticide
The internal pressure of aerosol insecticide is ≤ 1.0MPa.
Note: For the aerosols insecticide product equipped with a quantitative valve for an amount of below 50mL, the internal pressure will not be measured.
4.10 Net content of aerosols insecticide
It shall be clearly indicated on the tank body and marked with volume or mass unit. The deviation shall meet the requirements in attached Table 3 of Measures for the metrological supervision and administration of quantitatively packed commodities.
4.11 Net content of other formulations
It shall be clearly indicated on the product or package, marked with volume or mass unit. The deviation shall meet the requirements in attached Table 3 of Measures for the metrological supervision and administration of quantitatively packed commodities.
4.12 Hygienic indexes of repellent products
See Table 5 for hygienic indexes of repellent products that are in direct contact with human body.
Table 5 In mg/kg
Item Index
Methyl alcohol ≤2 000
Lead ≤10
Arsenic ≤2
Mercury ≤1
Cadmium ≤5
4.13 Safety requirements of clothing mothproofer products
Naphthalene shall not be detected from clothing mothproofer products.
5 Test method
5.1 Requirements for the use of active ingredients
Check whether there is a registration certificate for drug usage.
5.2 Toxicology
Provide the toxicological test report of the corresponding formulation in the “Provisions on pesticide registration data”.
5.3 Content of active ingredients and allowable fluctuation range
5.3.1 Check whether the content of active ingredients is clearly indicated on the product packaging.
5.3.2 The contents of active ingredients in mosquito coil, vaporizing mat, liquid vaporizer, aerosols insecticide and p-dichlorobenzene clothing mothproofer are tested according to those specified in Annex A, Annex B, Annex C, Annex D and Annex E respectively.
5.3.3 The contents of active ingredients in other formulations shall be tested according to the methods specified in QB/T 4147, QB/T 4148, QB/T 4149, QB/T 4150 or other corresponding standards.
5.4 Efficacy
Clothing mothproofers are tested according to NY/T 1151.1, the efficacy of other formulations is tested according to the methods specified in GB/T 13917.1 ~ 13917.9 or other corresponding standards, and the efficacy of mosquito coil, line incense, vaporizing mat, liquid vaporizer and aerosols insecticide products is tested by cylinder method.
5.5 Heat storage stability
5.5.1 Apparatus
5.5.1.1 Thermostat (or thermostatic water bath): (54±2)℃.
5.5.1.2 Ampoule bottle (or glass bottle with stopper that can be sealed at 54℃): 50mL.
5.5.1.3 Explosion-proof oven: control the temperature at (54±2)℃.
5.5.1.4 Balance: with a division value of not less than 0.01g.
5.5.2 Test steps of mosquito coil
After crushing the middle coil of a box of test samples, pass it through a 0.154mm (100 meshes/in) standard sorting sieve, put one half into an ampoule bottle and seal the bottle (the other half is used for determining the content of active ingredients), then put it in a thermostat at (54±2)℃ for 14d. After taking out the samples, test the content of active ingredients and calculate the degradation rate within 24h according to Annex A.
5.5.3 Test steps of vaporizing mat
Take the vaporizing mat in the same column of sealing bag (along the long side direction of vaporizing mat) as sample to determine the content of active ingredients before and after heat storage. Place the heat-stored samples (with packaging) in a thermostat at (54±2)℃ for 14d, after taking out the samples, test the content of active ingredients and calculate the degradation rate within 24h according to Annex B.
5.5.4 Test steps of liquid vaporizer
Take out a part of test sample from a bottle for determining the content of active ingredients, put the rest into an ampoule bottle and seal the bottle, then put it in a thermostat at (54±2)℃ for 14d. After taking out the sample, test the content of active ingredients and calculate the degradation rate within 24h according to Annex C.
5.5.5 Test steps of aerosols insecticide
Place the whole bottle of the test sample in an explosion-proof oven at (54±2)℃ for 14d. After taking out the sample, test the content of active ingredients and calculate the degradation rate within 24h according to Annex D.
5.5.6 Test steps of clothing mothproofer
Place the test sample of pyrethroid clothing mothproofer (with packaging) in a thermostat at (54±2)℃ for 14d. After taking out the sample, test the content of active ingredients and calculate the degradation rate within 24h according to Annex B.
Place a whole bag of test samples of p-dichlorobenzene clothing mothproofer in a thermostat at (54±2)℃ for 14d. After taking out the sample, test the content of active ingredients and calculate the degradation rate within 24h according to Annex E.
5.5.7 Degradation rate of active ingredients
It shall be calculated using Equation (1):
(1)
where,
P——the degradation rate, %;
m1——the content of active ingredients in the sample measured before heat storage;
m2——the content of active ingredients in the sample measured after heat storage.
5.5.8 Result judgment
If the degradation rate is rejected, a second test can be carried out for the sampled product from the same batch. If it is still rejected, this Item shall be judged as rejected.
5.5.9 Other formulations of products
They shall be tested according to the test methods in relevant national standards.
5.6 Smoke dust
The smoke dust shall be tested according to the method specified in GB/T 28015.
5.7 Minimum effective period of liquid vaporizer
It is tested in the temperature of (23±3)℃, with relative humidity of (65±15)%, and no strong convection air. (Test angle) unscrew the bottle cap of the liquid vaporizer, conduct the test by electrifying continuously (the liquid bottle is connected with a matching electric heater), and perform visual inspection until reaching the indicated minimum effective period, and observe whether the liquid contained in the bottle is in contact with the core rod to ensure that the product can be used longer than the minimum effective period. Test at least 3 bottles in parallel, and take the average of the effective period.
Foreword i
1 Scope
2 Normative references
3 Terms and definitions
4 Requirements
5 Test method
Annex A (Normative) Determination of the content of active ingredients of mosquito coil
Annex B (Normative) Determination of the content of active ingredients of vaporizing mat/pyrethroid clothing mothproofer
Annex C (Normative) Determination of the content of active ingredients of liquid vaporizer
Annex D (Normative) Determination method of active ingredients in aerosols insecticide
Annex E (Normative) Determination method of p-dichlorobenzene, o-dichlorobenzene and m-dichlorobenzene content
Annex F (Normative) Test method of naphthalene in clothing mothproofer
